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Showing papers on "Substitute natural gas published in 1975"


Patent
17 Oct 1975
TL;DR: In this paper, a process for the production of methane from methanol by catalytic dehydration and dehydrogenation providing a high initial methane yield and a final substitute natural gas product of high calorific value.
Abstract: A process is described for the production of methane from methanol by catalytic dehydration and dehydrogenation providing a high initial methane yield and a final substitute natural gas product of high calorific value. The catalytic dehydration and dehydrogenation steps may be effected simultaneously or in sequence. High efficiency in usage of raw materials and thermal requirements of the process are secured. A preferred catalyst containing both dehydration and dehydrogenation functions consists essentially of a major amount of iron oxide and minor amounts of chromium oxide and phosphate or tungstate ions.

61 citations


Patent
26 Nov 1975
TL;DR: In this paper, a carbonaceous material is introduced into a gasification zone, and the synthesis gas is passed sequentially through a water gas shift conversion zone, a sulfur compound and carbon dioxide removal zone, methanol synthesis zone and a methanation zone.
Abstract: Methanol and synthetic natural gas are produced concurrently by introducing a carbonaceous material into a gasification zone, and thereafter, passing sequentially the synthesis gas thus formed through a water gas shift conversion zone, a sulfur compound and carbon dioxide removal zone, a methanol synthesis zone and a methanation zone.

34 citations


Patent
01 Oct 1975
TL;DR: In this article, a carbonaceous material is converted to a fuel gas which is fungible with natural gas by a combination of steps comprising gasifying the carbon-baking material in the presence of air and carbon dioxide, purifying the effluent stream and separating carbon monoxide therefrom, catalytically reacting steam with the separated carbon dioxide and recovering a methane-rich product gas.
Abstract: A carbonaceous material is converted to a fuel gas which is fungible with natural gas by a combination of steps comprising gasifying the carbonaceous material in the presence of air and carbon dioxide, purifying the effluent stream and separating carbon monoxide therefrom, catalytically reacting steam with the separated carbon monoxide and recovering a methane-rich product gas

14 citations


Patent
03 Jun 1975
TL;DR: In this article, the poisoning of catalysts by impurities such as chloride was avoided by avoiding the injection of liquid methanol, as had been previously proposed, for cooling the hot gas.
Abstract: A process for producing a substitute natural gas from methanol, especially seaborne methanol liable to be contaminated with chloride, comprises catalytically reacting methanol vapor in a decomposition stage at an outlet temperature above 550° C, cooling the resulting gas by indirect heat exchange, preferably with water, to 250°-350° C, methanating the cooled gas with an outlet temperature of 500°-650° C, cooling the methanated gas by indirect heat exchange, preferably with methanol, and methanating the resulting gas in at least one further methanation stage. By avoiding the injection of liquid methanol, as had been previously proposed, for cooling the hot gas, the poisoning of catalysts by impurities such as chloride does not take place.

11 citations



Patent
07 Nov 1975
TL;DR: In this paper, synthetic natural gas and high octane motor fuel blending stock is produced by catalytically reforming naphtha at low severity to maximize production of aromatics and minimize hydrocracking, and then converting the remaining paraffins to methane in a methanation zone.
Abstract: Synthetic natural gas and high octane motor fuel blending stock is produced by catalytically reforming naphtha at low severity to maximize production of aromatics and minimize hydrocracking, and then converting the remaining paraffins to methane in a methanation zone. The effluent from the methanation zone is separated into synthetic natural gas and motor fuel blending stock.

8 citations


30 Sep 1975
TL;DR: The results of a study which surveyed various methods of hydrogen production using nuclear and fossil energy are presented in this article, where the authors provided a description of these methods, and efficiencies are calculated for each case.
Abstract: The results of a study which surveyed various methods of hydrogen production using nuclear and fossil energy are presented A description of these methods is provided, and efficiencies are calculated for each case The process designs of systems that utilize the heat from a general atomic high temperature gas cooled reactor with a steam methane reformer and feed the reformer with substitute natural gas manufactured from coal, using reforming temperatures, are presented The capital costs for these systems and the resultant hydrogen production price for these cases are discussed along with a research and development program

3 citations


01 Mar 1975
TL;DR: Although deregulation of the price of natural gas, accelerated drilling and leasing, etc. will temporarily increase gas supplies, there are only temporary solutions and the only long-range answer is the gasification of coal as discussed by the authors.
Abstract: Although deregulation of the price of natural gas, accelerated drilling and leasing, etc. will temporarily increase gas supplies and the importation of petroleum feedstocks and liquefied natural gas will also increase the near future supplies of natural gas (or its equivalent), there are only temporary solutions and the only long-range answer is the gasification of coal. In terms of efficiency of resource use, seventy percent of the heat in coal can be contained in the product gas, while the principal alternative (conversion to electricity) is only about half as efficient; also, high sulfur coals can be used in the process without causing air pollution (the sulfur may even be recovered as a by-product). Fuel gas derived from coal will cost more than natural gas and many problems may develop in determining the proper price, especially when the product is mixed with natural gas as seems likely in order to use the present distribution system (some of these problems are described briefly). (LTN)

1 citations


Proceedings ArticleDOI
01 Jan 1975

1 citations


Journal ArticleDOI
TL;DR: The work carried out at the Babcock and Wilcox Research Center focuses on developing a fully continuous single reactor gasification process as discussed by the authors, which has not been shown feasible on a continuous basis.
Abstract: The direct production of methane from heavy hydrocarbons and steam, also known as the single reactor concept, is in its early stages of development. The concept was originated at the University of Wyoming and for the last two years has seen considerable attention at the Babcock and Wilcox Company. The product gas from this reaction contains primarily methane as the combustible constituent, therefore showing promise for use as substitute natural gas (SNG). An economic comparison of this concept, in comparison of other gasification processes currently being developed to produce SNG, shows it to be a more attractive process. The main disadvantage is that the concept has not been shown feasible on a continuous basis. The work carried out at the Babcock and Wilcox Research Center focuses on developing a fully continuous single reactor gasification process. A catalyst survey was conducted to determine what catalyst could be used effectively in the production of methane from hydrogen and carbon monoxide...

1 citations