Showing papers on "Toluidines published in 2015"
TL;DR: In this paper, the reduction of o-, m-, and p-nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor is studied.
Abstract: The reduction of o-, m-, and p-nitrotoluenes in supercritical isopropanol over Al2O3 in a flow reactor is studied. It is shown that corresponding toluidines are major reaction products. Aromatic ring alkoxylation and N-alkylation products make a considerable contribution to the composition of reaction mixtures.
4 citations
TL;DR: A half-sandwich acetatoiridium(III) complex can activate two geminal C(sp3)H bonds of 2-methylaniline derivatives to produce a new dinuclear azametallacycle, (η5-1,2,3,4,5-pentamethylcyclopentadie...
Abstract: A half-sandwich acetatoiridium(III) complex can activate two geminal C(sp3)–H bonds of 2-methylaniline derivatives to produce a new dinuclear azametallacycle, (η5-1,2,3,4,5-pentamethylcyclopentadie...
4 citations
TL;DR: Isomeric bromotoluenes react with sodium bis(trimethylsilyl)amide through intermediate methylbenzynes, yielding N,N-bis(trimsilyl)-toluidines and rearrangement products.
Abstract: Isomeric bromotoluenes react with sodium bis(trimethylsilyl)amide through intermediate methylbenzynes, yielding N,N-bis(trimethylsilyl)toluidines and rearrangement products, N,2-bis(trimethylsilyl)toluidines The formation of the latter is a rare example of 1,3-migration of silyl group from nitrogen atom to aromatic carbon atom The rearrangement is favored by increased solvent polarity and elevated temperature The observed product ratio can be rationalized by DFT quantum chemical calculations
2 citations