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Showing papers on "Wieland–Miescher ketone published in 1983"


Journal ArticleDOI
TL;DR: In this paper, the Wieland-Miescher ketone analogues (3) and (4), each bearing an angular protected hydroxymethyl group, have been prepared by amino acid catalysed cyclisation of their cyclohexane-1,3-dione derivatives.
Abstract: The Wieland–Miescher ketone analogues (3) and (4), each bearing an angular protected hydroxymethyl group, have been prepared by the amino-acid catalysed cyclisation of their cyclohexane-1,3-dione derivatives (1) and (2); the optical purities and absolute configurations of (3) and (4) have been determined by applying the methoxy (trifluoromethyl)phenylacetate method and the c.d. exciton chirality method, respectively, to their mono-9-ol derivatives.

7 citations


Journal ArticleDOI
TL;DR: In this paper, Wieland Miescher par le dimethyl-2,2 propanediol on obtient un monoacetal that l'on reduit par Li/NH 3
Abstract: En traitant la cetone de Wieland Miescher par le dimethyl-2,2 propanediol on obtient un monoacetal que l'on reduit par Li/NH 3

4 citations