Simple indole alkaloids and those with a nonrearranged monoterpenoid unit

Reserpine: A Challenge for Total Synthesis of Natural Products

Determination des configurations par “dedoublement partiel”—III : Alcools steroides

Die sehr selektiven Reduktionen mit komplexen Borhydriden haben in letzter Zeit grose Bedeutung erlangt. Ahnlichkeiten und Unterschiede im Reduktionsvermogen dieser Verbindungen und anderer komplexer Metallhydride, beispielsweise des Lithium-aluminiumhydrids, werden aufgezeigt.

Neuere Methoden der präparativen organischen Chemie IV Anwendung von komplexen Borhydriden und von Diboran in der organischen Chemie

A stereocontrolled total synthesis of the indole diterpenoid natural product paspaline is described. Key steps include a highly diastereoselective enzymatic desymmetrization, substrate-directed epoxidation, Ireland-Claisen rearrangement, and diastereotopic group selective C–H acetoxylation to assemble the target with excellent stereofidelity. The route and results described herein outline complementary conceptual disconnections in the arena of steroid natural product synthesis.

A Global and Local Desymmetrization Approach to the Synthesis of Steroidal Alkaloids: Stereocontrolled Total Synthesis of Paspaline

Rauwolfia Alkaloids. XIX.1 The Constitution of Deserpidine and Reserpine

Direct Introduction of Oxygen into the Steroid Nucleus. I. Studies on the Chromic Anhydride Oxidation of Dehydroisoandrosterone Acetate Dibromide1

The Stereochemistry of Reserpine, Deserpidine and Related Alkaloids1,2

Rauwolfia Alkaloids. XV. The Constitution of Reserpic Acid: Position of Substituents in Ring E

Rauwolfia Alkaloids. XX.1 11-Methoxyalloyohimbane from Reserpine

A. F. St. André

Papers

Rauwolfia Alkaloids. XIX.1 The Constitution of Deserpidine and Reserpine

Direct Introduction of Oxygen into the Steroid Nucleus. I. Studies on the Chromic Anhydride Oxidation of Dehydroisoandrosterone Acetate Dibromide1

The Stereochemistry of Reserpine, Deserpidine and Related Alkaloids1,2

Rauwolfia Alkaloids. XV. The Constitution of Reserpic Acid: Position of Substituents in Ring E

Rauwolfia Alkaloids. XX.1 11-Methoxyalloyohimbane from Reserpine