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A. L. Sigan
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 6
Citations - 35
A. L. Sigan is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Aquation & Photosensitizer. The author has an hindex of 3, co-authored 6 publications receiving 31 citations.
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Journal ArticleDOI
Redox-active cobalt complexes as promising antitumor agents
S. Osinsky,I. Ya. Levitin,A. L. Sigan,L Bubnovskaya,I. I. Ganusevich,Luigi Campanella,P. Wardman +6 more
TL;DR: Cobalt(iii) complexes with tetradentate aliphatic Schiff"s bases containing also compounds of the vitamin PP series or their analogs as axial ligands were synthesized as potential antitumor agents and exhibit a strong antimetastatic effect.
Journal ArticleDOI
Hydroxyalkylation of 4,5,6,7-tetrahydroindole with polyfluorocarbonyl compounds as a route to 2-substituted indoles
A. L. Sigan,Dmitrii V. Gusev,N. D. Chkanikov,Elena Yu. Shmidt,A. V. Ivanov,Al’bina I. Mihaleva +5 more
TL;DR: The regioselective hydroxyalkylation of 4,5,6,7-tetrahydroindole at position 2 using highly electrophilic polyfluorocarbonyl compounds was performed for the first time as discussed by the authors.
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Novel Fluorinated Porphyrins Sensitize Tumor Cells to Photodamage in Normoxia and Hypoxia: Synthesis and Biocompatible Formulations.
Elizaveta V Belyaeva,Alina A. Markova,Dmitry N. Kaluzhny,A. L. Sigan,Lev L Gervitz,Aida N Ataeva,N. D. Chkanikov,Alexander A. Shtil +7 more
TL;DR: The authors' new fluorinated porphyrin derivatives, especially their emulsions in which the photosensitizer and the oxygenated medium are coupled into one phase, can be perspective for photoelimination of hypoxic tumor cells.
Journal ArticleDOI
Redox‐Active Cobalt Complexes as Promising Antitumor Agents.
S. Osinsky,I. Ya. Levitin,A. L. Sigan,L Bubnovskaya,I. I. Ganusevich,Luigi Campanella,P. Wardman +6 more
TL;DR: Cobalt(iii) complexes with tetradentate aliphatic Schiff bases containing also compounds of the vitamin PP series or their analogs as axial ligands were synthesized as potential antitumor agents as mentioned in this paper.
Journal ArticleDOI
Use of functionalized organocobalt initiators in processes of emulsion polymerization
I. A. Gritskova,Angelina Kolyachkina,Ilia Levitin,Elena Paskonova,A. L. Sigan,M. S. Tsar'kova +5 more
TL;DR: In this article, the pH-dependent initiators of emulsion polymerization were studied in water emulsions using styrene as a model monomer at various pH and temperatures, and the results showed that the resulting polymerization rates proved relatively low if both the length of carbon chain of the alkyl ligand and pH range favored extra chelation in the given initiator due to coordination of the functional group.