Cause, conseguenze e strategie di mitigazione Proponiamo il primo di una serie di articoli in cui affronteremo l’attuale problema dei mutamenti climatici. Presentiamo il documento redatto, votato e pubblicato dall’Ipcc - Comitato intergovernativo sui cambiamenti climatici - che illustra la sintesi delle ricerche svolte su questo tema rilevante.

/pdf/climate-change-2007-the-physical-science-basis-1x93ttz9jt.pdf

Climate Change 2007: The Physical Science Basis.

Plastic pollution is ubiquitous throughout the marine environment, yet estimates of the global abundance and weight of floating plastics have lacked data, particularly from the Southern Hemisphere and remote regions. Here we report an estimate of the total number of plastic particles and their weight floating in the world’s oceans from 24 expeditions (2007–2013) across all five sub-tropical gyres, costal Australia, Bay of Bengal and the Mediterranean Sea conducting surface net tows (N5680) and visual survey transects of large plastic debris (N5891). Using an oceanographic model of floating debris dispersal calibrated by our data, and correcting for wind-driven vertical mixing, we estimate a minimum of 5.25 trillion particles weighing 268,940 tons. When comparing between four size classes, two microplastic ,4.75 mm and meso- and macroplastic .4.75 mm, a tremendous loss of microplastics is observed from the sea surface compared to expected rates of fragmentation, suggesting there are mechanisms at play that remove ,4.75 mm plastic particles from the ocean surface.

/pdf/plastic-pollution-in-the-world-s-oceans-more-than-5-trillion-3xnj241yig.pdf

Plastic Pollution in the World's Oceans: More than 5 Trillion Plastic Pieces Weighing over 250,000 Tons Afloat at Sea

By 2050, the world is expected to generate 340 billion tons of waste annually, increasing drastically from today’s 201 billion tons What a Waste 20: A Global Snapshot of Solid Waste Management to 2050 aggregates extensive solid waste data at the national and urban levels It estimates and projects waste generation to 2030 and 2050 Beyond the core data metrics from waste generation to disposal, the report provides information on waste management costs, revenues, and tariffs; special wastes; regulations; public communication; administrative and operational models; and the informal sector

What a Waste 2.0: A Global Snapshot of Solid Waste Management to 2050

https://scholarlypublications.universiteitleiden.nl/access/item%3A2978611/view

Microplastics in freshwater and terrestrial environments: Evaluating the current understanding to identify the knowledge gaps and future research priorities.

https://bura.brunel.ac.uk/bitstream/2438/18351/1/FullText.pdf

An overview of chemical additives present in plastics: Migration, release, fate and environmental impact during their use, disposal and recycling.

The hypothesis that ‘microplastic will transfer hazardous hydrophobic organic chemicals (HOC) to marine animals’ has been central to the perceived hazard and risk of plastic in the marine environment. The hypothesis is often cited and has gained momentum, turning it into paradigm status. We provide a critical evaluation of the scientific literature regarding this hypothesis. Using new calculations based on published studies, we explain the sometimes contrasting views and unify them in one interpretive framework. One explanation for the contrasting views among studies is that they test different hypotheses. When reframed in the context of the above hypothesis, the available data become consistent. We show that HOC microplastic-water partitioning can be assumed to be at equilibrium for most microplastic residing in the oceans. We calculate the fraction of total HOC sorbed by plastics to be small compared to that sorbed by other media in the ocean. We further demonstrate consistency among (a) measured HOC tr...

Microplastic as a Vector for Chemicals in the Aquatic Environment: Critical Review and Model-Supported Reinterpretation of Empirical Studies

Enhanced desorption of persistent organic pollutants from microplastics under simulated physiological conditions.

https://researchportal.port.ac.uk/portal/files/3082039/Characterisation_Quantity_and_Sorptive_Properties.pdf

Characterisation, quantity and sorptive properties of microplastics extracted from cosmetics.

Competitive sorption of persistent organic pollutants onto microplastics in the marine environment.

Microplastics represent an increasing source of anthropogenic contamination in aquatic environments, where they may also act as scavengers and transporters of persistent organic pollutants. As estuaries are amongst the most productive aquatic systems, it is important to understand sorption behaviour and transport of persistent organic pollutants (POPs) by microplastics along estuarine gradients. The effects of salinity sorption equilibrium kinetics on the distribution coefficients (Kd) of phenanthrene (Phe) and 4,4′-DDT, onto polyvinyl chloride (PVC) and onto polyethylene (PE) were therefore investigated. A salinity gradient representing freshwater, estuarine and marine conditions, with salinities corresponding to 0 (MilliQ water, 690 μS/cm), 8.8, 17.5, 26.3 and 35 was used. Salinity had no significant effect on the time required to reach equilibrium onto PVC or PE and neither did it affect desorption rates of contaminants from plastics. Although salinity had no effect on sorption capacity of Phe onto plastics, a slight decrease in sorption capacity was observed for DDT with salinity. Salinity had little effect on sorption behaviour and POP/plastic combination was shown to be a more important factor. Transport of Phe and DDT from riverine to brackish and marine waters by plastic is therefore likely to be much more dependent on the aqueous POP concentration than on salinity. The physical characteristics of the polymer and local environmental conditions (e.g. plastic density, particle residence time in estuaries) will affect the physical transport of contaminated plastics. A transport model of POPs by microplastics under estuarine conditions is proposed. Transport of Phe and DDT by PVC and PE from fresh and brackish water toward fully marine conditions was the most likely net direction for contaminant transport and followed the order: Phe-PE >> DDT-PVC = DDT-PE >> Phe-PVC.

/pdf/transport-of-persistent-organic-pollutants-by-microplastics-3pmk4vgjp7.pdf

Adil Bakir

Papers

Microplastic as a Vector for Chemicals in the Aquatic Environment: Critical Review and Model-Supported Reinterpretation of Empirical Studies

Enhanced desorption of persistent organic pollutants from microplastics under simulated physiological conditions.

Characterisation, quantity and sorptive properties of microplastics extracted from cosmetics.

Competitive sorption of persistent organic pollutants onto microplastics in the marine environment.

Transport of persistent organic pollutants by microplastics in estuarine conditions