J. Appl. Cryst.の発刊に際して

1. Advantages of Chemical Redox Agents 878 2. Disadvantages of Chemical Redox Agents 879 C. Potentials in Nonaqueous Solvents 879 D. Reversible vs Irreversible ET Reagents 879 E. Categorization of Reagent Strength 881 II. Oxidants 881 A. Inorganic 881 1. Metal and Metal Complex Oxidants 881 2. Main Group Oxidants 887 B. Organic 891 1. Radical Cations 891 2. Carbocations 893 3. Cyanocarbons and Related Electron-Rich Compounds 894

/pdf/chemical-redox-agents-for-organometallic-chemistry-4fs84ntwp8.pdf

Chemical Redox Agents for Organometallic Chemistry

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

The chemistry of heterocyclic carbenes has experienced a rapid development over the last years. In addition to the imidazolin-2-ylidenes, a large number of cyclic diaminocarbenes with different ring sizes have been described. Aside from diaminocarbenes, P-heterocyclic carbenes, and derivatives with only one, or even no heteroatom within the carbene ring are known. New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclization of β-functionalized isocyanides have been developed recently. This review summarizes the new developments regarding the synthesis of N-heterocyclic carbenes and their metal complexes.

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

Keywords: Time-Resolved Fluorescence ; Resonance Energy-Transfer ; Near-Infrared Luminescence ; Double-Stranded Dna ; Prostate-Specific Antigen ; Photoinduced Electron-Transfer ; Europium-Tetracycline Complex ; Sybr-Green-I ; Terbium Complexes ; Optical Probes Reference EPFL-ARTICLE-149396doi:10.1021/cr900362eView record in Web of Science Record created on 2010-06-17, modified on 2017-05-12

Lanthanide Luminescence for Biomedical Analyses and Imaging

The complete manuscript of this communication appears in: Angew. Chem. Suppl. 1983, 1493. DOI:10.1002/anie.198314930

Synthesis and Structure of a Diarsenechromium Complex with an Unsupported Arsenic‐Arsenic Double Bond

Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C–C coupling catalysts and solvent effects in organic and aqueous media

Iron carbonyl complexes of some perfluoromethyl-substituted poly(phosphines)

An Ultraviolet Photoelectron Spectroscopic-Molecular Orbital Study of Some Cyclopolyphosphines

A l'etat solide les deux composes cristallisent respectivement dans les systemes triclinique et orthorhombique et presentent une stereochimie plane autour de l'azote. Les atomes de phosphore en solution et en phase gazeuse ont un caractere plus basique que dans l'analogue acyclique Me 2 NP(OMe) 2

Alan H. Cowley

Papers

Synthesis and Structure of a Diarsenechromium Complex with an Unsupported Arsenic‐Arsenic Double Bond

Bis(imino)acenaphthene (BIAN)-supported palladium(II) carbene complexes as effective C–C coupling catalysts and solvent effects in organic and aqueous media

Iron carbonyl complexes of some perfluoromethyl-substituted poly(phosphines)

An Ultraviolet Photoelectron Spectroscopic-Molecular Orbital Study of Some Cyclopolyphosphines

Stereoelectronic effects of cyclization in aminophosphine systems: structural, PES, and NMR study of Me2NP(OCH2)2CMe2 and CH2(CH2CH2)2NP(OCH2)2CMe2