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Alexander N. Kashin
Researcher at Moscow State University
Publications - 85
Citations - 769
Alexander N. Kashin is an academic researcher from Moscow State University. The author has contributed to research in topics: Catalysis & Reactivity (chemistry). The author has an hindex of 14, co-authored 85 publications receiving 757 citations. Previous affiliations of Alexander N. Kashin include Russian Academy of Sciences & A. N. Nesmeyanov Institute of Organoelement Compounds.
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Journal ArticleDOI
NC-palladacycles as highly effective cheap precursors for the phosphine-free Heck reactions
Irina P. Beletskaya,Alexander N. Kashin,N. B. Karlstedt,Anton V. Mitin,Andrei V. Cheprakov,Grigoriy M. Kazankov +5 more
TL;DR: In this paper, a cyclopalladated Pd2(μ-L)2(NC)2] palladacycle with OC coordination was proposed for the Heck reaction.
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Palladium Colloid Stabilized by Block Copolymer Micelles as an Efficient Catalyst for Reactions of C−C and C−Heteroatom Bond Formation
Irina P. Beletskaya,Alexander N. Kashin,A.E. Litvinov,Vladimir S. Tyurin,P.M. Valetsky,G. van Koten +5 more
TL;DR: Palladium nanoparticles stabilized in micelles formed by polystyrene-co-poly(ethylene oxide) and cetylpyridinium chloride as a surfactant were investigated as a catalyst in the following reactions: the Heck reaction of 2-ethylhexyl acrylate with iodobenzene and p-bromoacetophenone.
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Efficient and Recyclable Catalyst of Palladium Nanoparticles Stabilized by Polymer Micelles Soluble in Water for Suzuki-Miyaura Reaction, Ostwald Ripening Process with Palladium Nanoparticles
TL;DR: The Suzuki-Miyaura cross-coupling reaction of ArX (I, Br) with Ar′B(OH) 2, catalyzed by Pd-containing water-soluble micelle formed by PS-PEO copolymer and N-cetylpyridinium chloride as a surfactant, was studied in water and methanol as discussed by the authors.
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Structure and solvent effects in organomercuric electrochemistry. Polarographical scale of CH bond acidities
TL;DR: In this paper, a number of organomercuric compounds, R2Hg and RHgClO4, with different R groups have been studied by the polarographic method.
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Palladium-catalyzed arylation of sulfonyl CH-acids
TL;DR: In this paper, a method for the palladium-catalyzed monoarylation of a series of functionalized sulfones by aryl halides is described, which proceeds in the presence of 2 mol% of Pd 2 dba 3 ·CHCl 3 (dba=dibenzylideneacetone), PPh 3 and NaH as a base, only with relatively strong CH-acids and gives monoarylated products in moderate to high yields.