A
and Antonio Togni
Researcher at École Polytechnique Fédérale de Lausanne
Publications - 8
Citations - 215
and Antonio Togni is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Privacy policy & Negative liberty. The author has an hindex of 5, co-authored 5 publications receiving 210 citations.
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Journal ArticleDOI
Electronic Effects in Asymmetric Catalysis. Synthesis and Structure of Model Rhodium Complexes Containing Ferrocenyl Ligands for Use in the Hydroboration Reaction
TL;DR: A series of new rhodium complexes with chiral ferrocenyl chelating ligands containing a tertiary phosphine and a pyrazole moiety have been obtained in good yields from the reaction of the corresponding P,N ligand (1a−p) with [Rh(1,5-COD)2]BF4, [Rh (CO)2Cl]2, and [RH(COE)2CL]2] as discussed by the authors.
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Toward Metal-Mediated C−F Bond Formation. Synthesis and Reactivity of the 16-Electron Fluoro Complex [RuF(dppp)2]PF6 (dppp = 1,3-Bis(diphenylphosphino)propane)
TL;DR: The five-coordinate fluoro complex [RuF(dppp)2]PF6 (1a) has been prepared by reacting [RuCl[RuF2dplp]PF 6 (2aBPh4] with TlF [1,3-bis(diphenylphosphino)propane] as discussed by the authors, showing a distorted trigonal bipyramidal geometry.
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Catalytic Fluorination by Halide Exchange with 16-Electron Ruthenium(II) Complexes. X-ray Structure of [Tl(μ-F)2Ru(dppe)2]PF6
TL;DR: The 16-electron ruthenium(II) complexes [RuCl(dppe)2]PF6 (2; dppe = 1,2-bis(diphenylphosphino)ethane), [RuCL(chiraphos)2], PF6 (3; chiraphoses = (S,S)-3,4-bis (diphensylphophosphino), butane, and [Rucl(PNNP] as discussed by the authors
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Enantioselective Palladium-Catalyzed Hydrosilylation of Styrene: Detailed Reaction Mechanism from First-Principles and Hybrid QM/MM Molecular Dynamics Simulations
TL;DR: In this article, the enantioselective hydrosilylation of styrene catalyzed by Pd0 species generated in situ from dichloro[1]-(R)-1-[(S)-2(diphenylphosphino-kP)ferrocenyl]ethyl]-3-trimethylphenyl-5-1H-pyrazole-kN]palladium (1) was investigated in detail through ab initio mol. dynamics/mol.
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Rapid and Selective Electrophilic Trifluoromethylation of the 4,4‐Difluoro‐4‐bora‐3a,4a‐diaza‐s‐indacene (BODIPY) Scaffold
TL;DR: In this article, a rapid functionalization of the 4,4-difluoro-4-bora-3a,4a-diaza-sindacene (BODIPY) scaffold by means of electrophilic trifluoromethylation was reported.