A
Andrea Temperini
Researcher at University of Perugia
Publications - 159
Citations - 2370
Andrea Temperini is an academic researcher from University of Perugia. The author has contributed to research in topics: Diselenide & Enantioselective synthesis. The author has an hindex of 28, co-authored 158 publications receiving 2149 citations. Previous affiliations of Andrea Temperini include University of Calabria.
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Journal ArticleDOI
Asymmetric Azidoselenenylation of Alkenes: A Key Step for the Synthesis of Enantiomerically Enriched Nitrogen‐Containing Compounds
Marcello Tiecco,Lorenzo Testaferri,Claudio Santi,Cristina Tomassini,Francesca Marini,Luana Bagnoli,Andrea Temperini +6 more
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Novel azido-phenylselenenylation of double bonds. Evidence for a free-radical process
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Preparation of a new chiral non-racemic sulfur-containing diselenide and applications in asymmetric synthesis.
Marcello Tiecco,Lorenzo Testaferri,Claudio Santi,Cristina Tomassini,Francesca Marini,Luana Bagnoli,Andrea Temperini +6 more
TL;DR: The synthesis of the new chiral non-racemic sulfur-containing diselenide, di-2-methoxy-6-[(1S)-1-(methylthio)ethyl]phenyl diselENide, is described, which acts as a strong electrophilic reagent and adds to alkenes to afford the products of selenomethoxylation or selenohydroxylation, respectively, with excellent diastereoselectivities.
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New nitrogen containing chiral diselenides: synthesis and asymmetric addition reactions to olefins
Marcello Tiecco,Lorenzo Testaferri,Claudio Santi,Cristina Tomassini,Francesca Marini,Luana Bagnoli,Andrea Temperini +6 more
TL;DR: In this paper, a simple synthesis of two new nitrogen containing diselenides, 7 and 8, was described, and these compounds were employed as starting materials to effect the asymmetric methoxyselenenylation, the hydroxyselenensylation as well as the cyclofunctionalization of olefins.
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Alkynyl phenyl selenides as convenient precursors for the synthesis of stereodefined trisubstituted alkenes
Marco Tingoli,Marcello Tiecco,Lorenzo Testaferri,Andrea Temperini,Giancarlo Pelizzi,Alessia Bacchi +5 more
TL;DR: In this article, the addition of p-toluensulfonic acid to alkynyl phenyl selenides is regio-and stereospecific and affords (Z)-α-(phenylseleno)vinyl p-toensulfonates in good yield.