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Journal ArticleDOI

Asymmetric Azidoselenenylation of Alkenes: A Key Step for the Synthesis of Enantiomerically Enriched Nitrogen‐Containing Compounds

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This article is published in Angewandte Chemie.The article was published on 2003-07-14. It has received 109 citations till now. The article focuses on the topics: Azide & Enantioselective synthesis.

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Journal ArticleDOI

Organic Azides: An Exploding Diversity of a Unique Class of Compounds

TL;DR: In this Review, the fundamental characteristics of azide chemistry and current developments are presented and the focus will be placed on cycloadditions (Huisgen reaction), aza ylide chemistry, and the synthesis of heterocycles.
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Organoselenium chemistry: role of intramolecular interactions.

TL;DR: The subject of hypervalency has not attracted much attention and is the focus of this review of selenium chemistry, which has now become a well-established field of research.
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Organische Azide – explodierende Vielfalt bei einer einzigartigen Substanzklasse

TL;DR: Aza-Ylidchemie, Aza-wittig-Reaktion, Sundberg-Umlagerung, Staudinger-Ligation, Boyer-Boyer and Boyer Aube-Aube-UMLagerung as discussed by the authors, Curtius-Universität, Schmidt-Ummagerung sowie die Hemetsberger-Umbagerung zeugen von der Vielfaltigkeit moderner Azid-Chemie, and aktuelle Entwicklungen auf dem interdis
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Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols

TL;DR: A DFT calculation indicates that Mn catalyst plays key dual roles as an efficient catalyst for the generation of azido radical and a stabilizer for peroxyl radical intermediate, which provides a novel approach to high value-added β-azido alcohols.
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Metal-free radical azidoarylation of alkenes: rapid access to oxindoles by cascade C-N and C-C bond-forming reactions.

TL;DR: In this article, a new method for the oxidative radical azidation of alkenes relies on an azide in combination with a hypervalent iodine reagent, which was shown to be effective in the case of a single alken.
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