Dielectric-barrier discharges (silent discharges) are used on a large industrial scale. They combine the advantages of non-equilibrium plasma properties with the ease of atmospheric-pressure operation. A prominent feature is the simple scalability from small laboratory reactors to large industrial installations with megawatt input powers. Efficient and cost-effective all-solid-state power supplies are available. The preferred frequency range lies between 1 kHz and 10 MHz, the preferred pressure range between 10 kPa and 500 kPa. Industrial applications include ozone generation, pollution control, surface treatment, high power CO2 lasers, ultraviolet excimer lamps, excimer based mercury-free fluorescent lamps, and flat large-area plasma displays. Depending on the application and the operating conditions the discharge can have pronounced filamentary structure or fairly diffuse appearance. History, discharge physics, and plasma chemistry of dielectric-barrier discharges and their applications are discussed in detail.

https://www3.nd.edu/~sst/teaching/AME60637/reading/2003_PCPP_Kogelschatz_dbd_review.pdf

Dielectric-barrier Discharges: Their History, Discharge Physics, and Industrial Applications

Laser-induced breakdown spectroscopy (LIBS) has become a very popular analytical method in the last decade in view of some of its unique features such as applicability to any type of sample, practically no sample preparation, remote sensing capability, and speed of analysis The technique has a remarkably wide applicability in many fields, and the number of applications is still growing From an analytical point of view, the quantitative aspects of LIBS may be considered its Achilles' heel, first due to the complex nature of the laser–sample interaction processes, which depend upon both the laser characteristics and the sample material properties, and second due to the plasma–particle interaction processes, which are space and time dependent Together, these may cause undesirable matrix effects Ways of alleviating these problems rely upon the description of the plasma excitation-ionization processes through the use of classical equilibrium relations and therefore on the assumption that the laser-induced 

Laser-Induced Breakdown Spectroscopy (LIBS), Part I: Review of Basic Diagnostics and Plasma–Particle Interactions: Still-Challenging Issues Within the Analytical Plasma Community

Barrier discharges, also known as dielectric-barrier discharges or silent discharges, provide a simple technology to establish nonequilibrium plasma conditions in atmospheric-pressure gases. This property has led to a number of industrial applications, including ozone generation, surface modification, pollution control, CO/sub 2/ lasers, excimer lamps, and flat plasma-display panels. Depending on a variety of gas properties, operating parameters, and boundary conditions, the discharge can exhibit pronounced filamentary character, self-organized regular-discharge patterns, or completely diffuse appearance. The literature on these different types of barrier discharges is reviewed, and the underlying physical phenomena are discussed. Relative recent investigations on low-current density diffuse barrier discharges suggest novel applications of fairly "mild" plasmas for sterilization and disinfection purposes and utilizing their selective influence on biological cells.

Filamentary, patterned, and diffuse barrier discharges

The overwhelming scatter which occurs when optical radiation propagates through tissue severely limits the ability to image internal structure using measurements of transmitted intensity. A broad range of methods has been proposed during the past decade or so in order to improve imaging performance. Direct methods involve isolating an unscattered or least-scattered component of transmitted scattered light. Indirect methods generally involve measuring some characteristic of the temporal distribution of transmitted light, or an equivalent in the frequency domain, and obtaining a computational solution to the inverse problem. In this paper, we review the experimental techniques which have been proposed in order to explore both direct and indirect imaging. The relative merits and limitations of the various experimental methods are discussed, and we consider the future directions and likelihood of success of optical imaging in medicine.

https://iopscience.iop.org/article/10.1088/0031-9155/42/5/007/pdf

Optical imaging in medicine: I. Experimental techniques.

An overview is given of recent developments in laser diagnostic methods for the quantitative measurement of trace species concentrations and, in conjunction, of temperature in combustion systems. After a short introduction illustrating some experiments from the pre-laser era, the article presents typical applications and discusses advantages and limitations of laser techniques including laser absorption, linear, saturated, predissociative and multi-photon-excited laser-induced fluorescence (LIF), resonance-enhanced multiphoton ionization (REMPI), electronically resonant coherent anti-Stokes Raman scattering (resonance CARS), degenerate four-wave mixing (DFWM) and amplified spontaneous emission (ASE). Recent trends including two-dimensional imaging, multi-species detection and high-pressure applications will also be discussed. Throughout the article, an attempt is made to present typical results from a large portion of the relevant technical literature. A concluding section gives a short summary of the current status and comments on the perspectives for further research.

Laser Techniques for the Quantitative Detection of Reactive Intermediates

A sensing apparatus (10) consisting of more than one diode laser (12) having select lasing frequencies, a multiplexer (16) optically coupled to the outputs of the diode lasers with the multiplexer being further optically coupled to a pitch side optical fiber. Multiplexed laser light is transmitted through the pitch side optical fiber to a pitch optic (20) operatively associated with a process chamber (22) which may be a combustion chamber or the boiler of a coal or gas fired power plant. The pitch optic (20) is oriented to project multiplexed laser output through the process chamber. Also operatively oriented with the process chamber is a catch optic (24) in optical communication with the pitch optic to receive the multiplexed laser output projected through the process chamber. The catch optic (24) is optically coupled to an optical fiber which transmits the multiplexed laser output to a demultiplexer (28). The demultiplexer (28) demultiplexes the laser light and optically couples the select lasing frequencies of light to a detector (25) with the detector being sensitive to one of the select lasing frequencies.

Method and apparatus for the monitoring and control of combustion

Optical imaging through turbid media is demonstrated using a degenerate four-wave mixing correlation time gate. An apparatus and method for detecting ballistic and/or snake light while rejecting unwanted diffusive light for imaging structures within highly scattering media are described. Degenerate four-wave mixing (DFWM) of a doubled YAG laser in rhodamine 590 is used to provide an ultrafast correlation time gate to discriminate against light that has undergone multiple scattering and therefore has lost memory of the structures within the scattering medium. Images have been obtained of a test cross-hair pattern through highly turbid suspensions of whole milk in water that are opaque to the naked eye, which demonstrates the utility of DFWM for imaging through turbid media. Use of DFWM as an ultrafast time gate for the detection of ballistic and/or snake light in optical mammography is discussed.

Optical imaging through turbid media with a degenerate four-wave mixing correlation time gate

Barrier discharges in humid air generate large quantities of OH and are well suited for the treatment of gas-based pollutants. In order to understand and optimize the formation and utilization of OH, we have imaged the spatial and temporal distribution of the OH radical with resolution of 40 /spl mu/m and 100 ns. Using a flowing mix of Ar/O/sub 2//H/sub 2/O (78.5/20/1.5), we have found that OH exists only within the 85-/spl mu/m radius channel formed by the transient microdischarge. At modest power densities of 0.1 W/cm/sup 2/, over l0/sup 6//cm/sup 2//s of these small filaments quickly fill the entire reactor volume.

Distribution of OH within silent discharge plasma reactors

Planar laser‐induced fluorescence (PLIF) is used to monitor Cu atoms and Cu2 produced by excimer laser ablation of a copper target (308 nm, ≳10 J/cm2, 1–3 GW/cm2) expanding rapidly into helium background gas at pressures ranging from 10 to 100 Torr. The Cu2 results from gas phase condensation of the copper atoms ablated from the target in the regions of highest Cu atom density as expected, but the maximum Cu2 laser‐induced fluorescence (LIF) signal occurs significantly after the maximum of the Cu signal. Rotationally resolved excitation scans of Cu2 utilizing the A–X (0,0) transition indicate that the Cu2 has reached equilibrium with the 300 K background gas. An extensive search for Cu3 via LIF failed, indicating that Cu3 is present only in very low ‘‘steady state’’ number density in the plume. This data is explained qualitatively by a simple kinetic model. In addition to the kinetic information, it is clear from the PLIF images that viscous eddy formation becomes more pronounced as the backing gas pressu...

Planar laser‐induced fluorescence imaging of Cu atom and Cu2 in a condensing laser‐ablated copper plasma plume

A method for measuring combustion parameters within a combustion zone of a gas turbine engine, the combustion zone being defined between an inner and outer casing. The method comprises transmitting a beam from a transmit optic optically coupled to a bore in the outer casing off a portion of the inner casing and receiving a portion of the beam reflected off the inner casing with a receiving optic optically coupled to a bore in the outer casing. An apparatus for practicing the method comprises a laser generating a beam and a transmitting/receiving optics pair, the transmitting/receiving optics pair being configured for operative association with a port in an outer casing of a gas turbine engine, whereby the transmitting/receiving optics are in optical communication by reflecting the beam off a portion of an inner casing.

Andrew D. Sappey

Papers

Method and apparatus for the monitoring and control of combustion

Optical imaging through turbid media with a degenerate four-wave mixing correlation time gate

Distribution of OH within silent discharge plasma reactors

Planar laser‐induced fluorescence imaging of Cu atom and Cu2 in a condensing laser‐ablated copper plasma plume

Method and apparatus for spectroscopic measurements in the combustion zone of a gas turbine engine