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Andrew R. Gibbs
Researcher at University of Oxford
Publications - 8
Citations - 378
Andrew R. Gibbs is an academic researcher from University of Oxford. The author has contributed to research in topics: Enantioselective synthesis & Cyclopentene. The author has an hindex of 5, co-authored 8 publications receiving 366 citations. Previous affiliations of Andrew R. Gibbs include University of Reading.
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Journal ArticleDOI
Enantioselective desymmetrisation of achiral epoxides
Journal ArticleDOI
Mechanism and applications of lithium amide-induced asymmetric rearrangements of 4-substituted and 4,4-disubstituted cyclopentene oxides to cyclopentenols
TL;DR: In this article, the deprotonation mechanism of 1,2-dideuterated 4-substituted cyclopentene oxides has been investigated and lithium amide-induced rearrangements of these oxides are described.
Journal ArticleDOI
An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin
David M. Hodgson,Andrew R. Gibbs +1 more
Journal ArticleDOI
Highly enantioselective rearrangement of quaternary carbon-containing meso-epoxides to allylic alcohols
TL;DR: In this paper, the asymmetric synthesis of 4-substituted cis-4-(hydroxymethyl)cyclopent-2-en-1-ols 3 (R = alkyl, benzyloxymethyl), via highly enantioselective rearrangement of 3-substrained cis-6-oxabicyclo[3.1.0]hexane-3-methanols 1
Journal ArticleDOI
On the mechanism of lithium amide-induced rearrangements of 4-substituted cyclopentene oxides to cyclopentenols
David M. Hodgson,Andrew R. Gibbs +1 more
TL;DR: In this article, the preparation and lithium amide-induced rearrangements of epoxides 4, 10 (R = Bn, TBS) are described, providing insight into the rearrangement mechanisms which operate in such systems.