Journal ArticleDOI
An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin
David M. Hodgson,Andrew R. Gibbs +1 more
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This article is published in Synlett.The article was published on 1997-06-01. It has received 22 citations till now. The article focuses on the topics: Claisen rearrangement & Iridomyrmecin.read more
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Recent developments in the synthesis of prostaglandins and analogues.
Journal ArticleDOI
New and highly enantioselective catalysts for the rearrangement of meso-epoxides into chiral allylic alcohols
TL;DR: New and highly enantioselective catalysts for the rearrangement of meso-epoxides into chiral allylic alcohols were proposed in this paper, where they were used for chiral alignment.
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Synthesis of novel spinosyn A analogues by Pd-mediated transformations.
TL;DR: A convergent approach towards novel enantiopure spinosyn A analogues of type 3 is described, which is based on investigations of structure-activity relationships and employs a twofold Heck reaction as key step for the preparation of the tricyclic backbone assembly.
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A novel mixed dimer of a norephedrine-derived chiral lithium amide and 2-lithium-1-methylimidazole, and catalytic enantioselective deprotonation of cyclohexene oxide.
TL;DR: Investigations by 1H, 6Li and 13C NMR of the 6Li/15N isotopologue 8 of 6 have shown that 6 is homodimeric in THF and that, in the presence of 2, it forms a novel heterodimer 10.