Anna Grabarz

TL;DR: The photophysical properties of 1-benzoylmethyleneisoquinoline derivatives differ from those of quinolines, and the most pronounced differences are found for the fluorescence quantum yields.

TL;DR: A series of difluoroboranyls derived from amides carrying a variable π-conjugated spacer between the electron-donating and electron-accepting groups was synthesized and characterized with (1)H, (11)B, (13)C, (15)N, and (19)F NMR, electronic absorption, fluorescence spectroscopies, and first-principle calculations.

TL;DR: A new series of phenantridine-based substituted difluoroboranyls is presented, revealing that both the nature of the substituent and its position on the phenyl ring significantly impact the magnitude of the electronic charge transferred upon excitation.

TL;DR: It is shown that the sulfur-containing compound has a much smaller emission quantum yield than its oxygen counterpart and the fluorescence quantum yield is much higher upon formation of the difluoroboranyl complex.

TL;DR: The pairing ofTFH3 with a TH2 CH3 - anion, where T represents tetrel atoms C, Si, Ge, Sn, Pb, results in a strong direct interaction between the two T atoms, which induces a rearrangement in the TFH3 molecule from tetrahedral to trigonal pyramidal.