A
Anne Boussonnière
Researcher at Centre national de la recherche scientifique
Publications - 28
Citations - 419
Anne Boussonnière is an academic researcher from Centre national de la recherche scientifique. The author has contributed to research in topics: Radical cyclization & Hydroboration. The author has an hindex of 10, co-authored 26 publications receiving 374 citations. Previous affiliations of Anne Boussonnière include University of Pittsburgh & University of Maine.
Papers
More filters
Journal ArticleDOI
Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene Boranes
Aleksandrs Prokofjevs,Anne Boussonnière,Linfeng Li,Hélène Bonin,Emmanuel Lacôte,Dennis P. Curran,Edwin Vedejs +6 more
TL;DR: Treatment of alkenes such as 3-hexene, 3-octene, and 1-cyclohexyl-1-butene with the N-heterocyclic carbene (NHC)-derived borane 2 and catalytic HNTf(2) (Tf = trifluoromethanesulfonyl (CF(3)SO(2))) effects hydroboration at room temperature.
Journal ArticleDOI
The Parent Borylene: Betwixt and Between
TL;DR: Reduction of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene dichloroborane and the related dimesityl derivative provide novel C-H insertion products that may have arisen from a borylene.
Journal ArticleDOI
Borenium-Catalyzed Hydroborations of Silyl-Substituted Alkenes and Alkynes with a Readily Available N-Heterocyclic Carbene–Borane
TL;DR: Borenium-catalyzed hydroboration reactions of a stable, readily available N-heterocyclic carbene-borane with allyl-, alkenyl-, and alkynylsilane substrates provides either standard 1,2-hydroboration products or rearranged 1,1-hydrobation products, depending on the structure of the substrate as discussed by the authors.
Journal ArticleDOI
Molecular iodine initiates hydroborations of alkenes with N-heterocyclic carbene boranes.
TL;DR: The hydroboration of alkenes of diverse structural types by assorted N-heterocyclic carbene boranes can be accomplished by addition of 5-10% diiodine by describing a new reaction.
Journal ArticleDOI
Radical cyclization of α-bromo aluminum acetals onto alkenes and alkynes (radic[Al] process): a simple access to γ-lactols and 4-methylene-γ-lactols.
TL;DR: Highly acid-sensitive lactols are prepared in a concise manner by using a radical cyclization of aluminum acetals, leading to synthetically useful building blocks, such as 1,4-diols, 1, 4-dienes, γ-lactones, and polysubstituted tetrahydrofurans.