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Anthony F. Cozzolino
Researcher at Texas Tech University
Publications - 48
Citations - 2524
Anthony F. Cozzolino is an academic researcher from Texas Tech University. The author has contributed to research in topics: Supramolecular chemistry & Density functional theory. The author has an hindex of 19, co-authored 44 publications receiving 2121 citations. Previous affiliations of Anthony F. Cozzolino include McMaster University & Massachusetts Institute of Technology.
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Selective turn-on ammonia sensing enabled by high-temperature fluorescence in metal-organic frameworks with open metal sites.
TL;DR: A heretofore unrecognized, yet potentially general property of many rigid, fluorescent MOFs is described and portend new applications for these materials in selective sensors, with selectivity profiles that can be tuned as a function of temperature.
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Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal–Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission
Natalia B. Shustova,Ta-Chung Ong,Anthony F. Cozzolino,Vladimir K. Michaelis,Robert G. Griffin,Mircea Dincă +5 more
TL;DR: It is shown that a perdeuterated TPE-based metal-organic framework (MOF) serves as an excellent platform for studying the low-energy vibrational modes of AIE-type chromophores, and a set of design criteria for the development of tunable turn-on porous sensors constructed from AIe-type molecules is proposed.
Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal–Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission
Natalia B. Shustova,Ta-Chung Ong,Anthony F. Cozzolino,Vladimir K. Michaelis,Robert G. Griffin,Mircea Dincă +5 more
TL;DR: In this paper, a perdeuterated tetraphenylethylene (TPE) based metal-organic framework was used to study the low-energy vibrational modes of aggregation-induced emission (AIE) type chromophores.
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The nature of the supramolecular association of 1,2,5-chalcogenadiazoles.
TL;DR: In this paper, the relativistic density functional theory was applied to the 1,2,5-chalcogenadiazoles and showed that tellurium derivatives possess the strongest association energies; these are so large that the binding strength is comparable to some hydrogen bonds.
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A survey of tellurium-centered secondary-bonding supramolecular synthons
TL;DR: The structural motifs assembled in these systems fall within eight general categories, from single to multiple-bonded supramolecular synthons as mentioned in this paper, and the overall structures assembled by the most important tellurium-based SISs and prospects for their application in crystal engineering are discussed.