Showing papers by "Arthur D. Pelton published in 2013"
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TL;DR: The sections in this article are as discussed by the authors, where the authors discuss Gibbs Energy and Equilibrium, Gibbs Energy of Mixing, Chemical Potential, and Chemical Equilibrium of Gibbs Energy.
Abstract: The sections in this article are
Introduction
Notation
Gibbs Energy and Equilibrium
Gibbs Energy
Chemical Equilibrium
Predominance Diagrams
Calculation of Predominance Diagrams
Ellingham Diagrams as Predominance Diagrams
Discussion of Predominance Diagrams
Thermodynamics of Solutions
Gibbs Energy of Mixing
Chemical Potential
Tangent Construction
Gibbs–Duhem Equation
Relative Partial Properties
Activity
Ideal Raoultian Solutions
Excess Properties
Activity Coefficient
Multicomponent Solutions
Binary Phase Diagrams
Systems with Complete Solid and Liquid Miscibility
Thermodynamic Origin of Phase Diagrams
Pressure–Composition Phase Diagrams
Minima and Maxima in Two-Phase Regions
Miscibility Gaps
Simple Eutectic Systems
Regular Solution Theory
Thermodynamic Origin of Simple Phase Diagrams Illustrated by Regular Solution Theory
Immiscibility–Monotectics
Intermediate Phases
Limited Mutual Solubility–Ideal Henrian Solutions
Geometry of Binary Phase Diagrams
Application of Thermodynamics to Phase Diagram Analysis
Thermodynamic/Phase Diagram Optimization
Polynomial Representation of Excess Properties
Least-Squares Optimization
Calculation of Metastable Phase Boundaries
Ternary and Multicomponent Phase Diagrams
The Ternary Composition Triangle
Ternary Space Model
Polythermal Projections of Liquidus Surfaces
Ternary Isothermal Sections
Topology of Ternary Isothermal Sections
Ternary Isopleths (Constant Composition Sections)
Quasi-Binary Phase Diagrams
Multicomponent Phase Diagrams
Nomenclature for Invariant Reactions
Reciprocal Ternary Phase Diagrams
Phase Diagrams with Potentials as Axes
General Phase Diagram Geometry
General Geometrical Rules for All True Phase Diagram Sections
Zero Phase Fraction Lines
Choice of Axes and Constants of True Phase Diagrams
Tie-lines
Corresponding Phase Diagrams
Theoretical Considerations
Other Sets of Conjugate Pairs
Solution Models
Sublattice Models
All Sublattices Except One Occupied by Only One Species
Ionic Solutions
Interstitial Solutions
Ceramic Solutions
The Compound Energy Formalism
Non-Stoichiometric Compounds
Polymer Solutions
Calculation of Limiting Slopes of Phase Boundaries
Short-Range Ordering
Long-Range Ordering
Calculation of Ternary Phase Diagrams From Binary Data
Minimization of Gibbs Energy
Phase Diagram Calculation
Bibliography
Phase Diagram Compilations
Thermodynamic Compilations
General Reading
30 citations
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TL;DR: In this paper, a model for the viscosity of silicate melts is proposed to describe and predict viscosities of oxide melts containing manganese and oxide oxide oxide.
Abstract: Our recently developed model for the viscosity of silicate melts is applied
to describe and predict the viscosities of oxide melts containing manganese
oxide. The model requires three pairs of adjustable parameters that describe
the viscosities in three systems: pure MnO, MnO-SiO2 and MnO-Al2O3-SiO2. The
viscosity of other ternary and multicomponent silicate melts containing MnO
is then predicted by the model without any additional adjustable model
parameters. Experimental viscosity data are reviewed for melts formed by MnO
with SiO2, Al2O3, CaO, MgO, PbO, Na2O and K2O. The deviation of the available
experimental data from the viscosities predicted by the model is shown to be
within experimental error limits.
8 citations
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TL;DR: The first-melting projection of a ternary or higher-order system shows the temperature at which a liquid phase first appears upon heating at any given composition in a system at thermodynamic equilibrium.
6 citations
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TL;DR: In this paper, a modified quasi-chemical model (MQM) was used to estimate the shape of liquid miscibility gaps in binary alloys using only a very few temperature-independent coefficients.
5 citations