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Showing papers by "Barbara A. Bekins published in 2007"


Journal ArticleDOI
TL;DR: In this paper, an off-road diesel spill (Mandan, ND) and a crude oil spill (Bemidji, MN) experiencing methanogenic biodegradation were previously shown to be undergoing an unexpected progression of homologous nalkane and n-alkylated cyclohexane loss.

31 citations


Journal ArticleDOI
01 Aug 2007-Geology
TL;DR: In this article, the retrograde solubility of calcium carbonate and cooling of basement fluids during ascent was estimated for the dissolution capacity of the venting fluids, and a comparison with typical equatorial Pacific carbonate mass accumulation rates showed that this mechanism is feasible.
Abstract: Recent observations indicate that curious closed depressions in carbonate sediments overlying basement edifices are widespread in the equatorial Pacific. A possible mechanism for their creation is dissolution by fluids exiting basement vents from off-axis hydrothermal flow. Quantitative analysis based on the retrograde solubility of calcium carbonate and cooling of basement fluids during ascent provides an estimate for the dissolution capacity of the venting fluids. Comparison of the dissolution capacity and fluid flux with typical equatorial Pacific carbonate mass accumulation rates shows that this mechanism is feasible. By maintaining sediment-free basement outcrops, the process may promote widespread circulation of relatively unaltered seawater in the basement in an area where average sediment thicknesses are 300–500 m. The enhanced ventilation can explain several previously puzzling observations in this region, including anomalously low heat flux, relatively unaltered seawater in the basement, and aerobic and nitrate-reducing microbial activity at the base of the sediments.

26 citations