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Bernd Plietker
Researcher at University of Stuttgart
Publications - 187
Citations - 5305
Bernd Plietker is an academic researcher from University of Stuttgart. The author has contributed to research in topics: Catalysis & Allylic rearrangement. The author has an hindex of 43, co-authored 182 publications receiving 4807 citations. Previous affiliations of Bernd Plietker include Stanford University & Dresden University of Technology.
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Journal ArticleDOI
Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen
Emil Roduner,Wolfgang Kaim,Biprajit Sarkar,Vlada B. Urlacher,Jürgen Pleiss,Roger Gläser,Wolf-Dietrich Einicke,Georg A. Sprenger,Uwe Beifuß,Elias Klemm,Christian Liebner,H. Hieronymus,Shih-Fan Hsu,Bernd Plietker,Sabine Laschat +14 more
TL;DR: Theoretical work on catalyst precursors, resting states, and elementary steps, as well as model reactions complemented by spectroscopic studies provide detailed insight into the molecular mechanisms of oxidation catalyses and pave the way for preparative applications.
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Palladium-catalyzed asymmetric addition of pronucleophiles to allenes.
TL;DR: A new approach for asymmetric allylic alkylations of carbon pronucleophiles by simple additions provides a very efficient, more atom economic strategy for asymmetrical C-C bond formation.
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A highly regioselective salt-free iron-catalyzed allylic alkylation.
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Fe-catalyzed allylic C-C-bond activation: vinylcyclopropanes as versatile a1,a3,d5-synthons in traceless allylic substitutions and [3 + 2]-cycloadditions.
TL;DR: The low-valent iron complex Bu(4)N[Fe(CO)(3)(NO)] (TBAFe) catalyzes the allylic C-C-bond activation of electron-poor vinyl cyclopropanes to generate synthetically useful a1,a3,d5-synthons which are prone to undergo multiple consecutive reactions.