Owing to their atomic layer thickness, strong light–material interaction, high nonlinearity, broadband optical response, fast relaxation, controllable optoelectronic properties, and high compatibility with other photonic structures, 2D materials, including graphene, transition metal dichalcogenides and black phosphorus, have been attracting increasing attention for photonic applications. By tuning the carrier density via electrical or optical means that modifies their physical properties (e.g., Fermi level or nonlinear absorption), optical response of the 2D materials can be instantly changed, making them versatile nanostructures for optical modulation. Here, up-to-date 2D material-based optical modulation in three categories is reviewed: free-space, fiber-based, and on-chip configurations. By analysing cons and pros of different modulation approaches from material and mechanism aspects, the challenges faced by using these materials for device applications are presented. In addition, thermal effects (e.g., laser induced damage) in 2D materials, which are critical to practical applications, are also discussed. Finally, the outlook for future opportunities of these 2D materials for optical modulation is given.

2D Materials for Optical Modulation: Challenges and Opportunities.

2D Layered Materials: Synthesis, Nonlinear Optical Properties, and Device Applications

As elemental main group materials (i.e., silicon and germanium) have dominated the field of modern electronics, their monolayer 2D analogues have shown great promise for next-generation electronic materials as well as potential game-changing properties for optoelectronics, energy, and beyond. These atomically thin materials composed of single atomic variants of group III through group VI elements on the periodic table have already demonstrated exciting properties such as near-room-temperature topological insulation in bismuthene, extremely high electron mobilities in phosphorene and silicone, and substantial Li-ion storage capability in borophene. Isolation of these materials within the postgraphene era began with silicene in 2010 and quickly progressed to the experimental identification or theoretical prediction of 15 of the 18 main group elements existing as solids at standard pressure and temperatures. This review first focuses on the significance of defects/functionalization, discussion of different allotropes, and overarching structure-property relationships of 2D main group elemental materials. Then, a complete review of emerging applications in electronics, sensing, spintronics, plasmonics, photodetectors, ultrafast lasers, batteries, supercapacitors, and thermoelectrics is presented by application type, including detailed descriptions of how the material properties may be tailored toward each specific application.

Emerging Applications of Elemental 2D Materials

2D phosphorene, arsenene, antimonene, and bismuthene, as a fast-growing family of 2D monoelemental materials, have attracted enormous interest in the scientific community owing to their intriguing structures and extraordinary electronic properties. Tuning the monoelemental crystals into bielemental ones between group-VA elements is able to preserve their advantages of unique structures, modulate their properties, and further expand their multifunctional applications. Herein, a review of the historical work is provided for both theoretical predictions and experimental advances of 2D V-V binary materials. Their various intriguing electronic properties are discussed, including band structure, carrier mobility, Rashba effect, and topological state. An emphasis is also given to their progress in fabricated approaches and potential applications. Finally, a detailed presentation on the opportunities and challenges in the future development of 2D V-V binary materials is given.

2D V-V Binary Materials: Status and Challenges.

Few-layer bismuthene is an emerging two-dimensional material in the fields of physics, chemistry, and material science. However, its nonlinear optical property and the related photonics device have been seldom studied so far. Here, we demonstrate a sub-200 fs soliton mode-locked erbium-doped fiber laser (EDFL) using a microfiber-based bismuthene saturable absorber for the first time, to the best of our knowledge. The bismuthene nanosheets are synthesized by the sonochemical exfoliation method and transferred onto the taper region of a microfiber by the optical deposition method. Stable soliton pulses centered at 1561 nm with the shortest pulse duration of about 193 fs were obtained. Our findings unambiguously imply that apart from its fantastic electric and thermal properties, few-layer bismuthene may also possess attractive optoelectronic properties for nonlinear photonics, such as mode-lockers, Q-switchers, optical modulators and so on.

Sub-200 fs soliton mode-locked fiber laser based on bismuthene saturable absorber

Ultrafast lasers play an important role in a variety of applications ranging from optical communications to medical diagnostics and industrial materials processing. Graphene and other two-dimensional (2D) noncarbon materials, including topological insulators (TIs), transition metal dichalcogenides (TMDCs), phosphorene, bismuthene, and antimonene, have witnessed a very fast development of both fundamental and practical aspects in ultrafast photonics since 2009. Their unique nonlinear optical properties enable them to be used as excellent saturable absorbers (SAs) that have fast responses and broadband operation, and can be easily integrated into lasers. Here, we catalog and review recent progress in the exploitation of these 2D noncarbon materials in this emerging field. The fabrication techniques, nonlinear optical properties, and device integration strategies of 2D noncarbon materials are first introduced with a comprehensive view. Then, various mode-locked/Q-switched lasers (e.g., fiber, solid-state, disk, and waveguide lasers) based on 2D noncarbon materials are reviewed. In addition, versatile soliton pulses generated from the mode-locked fiber lasers based on 2D noncarbon materials are also summarized. Finally, future challenges and perspectives of 2D materials-based lasers are addressed.

/pdf/2d-noncarbon-materials-based-nonlinear-optical-devices-for-15q5sj2vl2.pdf

2D noncarbon materials-based nonlinear optical devices for ultrafast photonics [Invited]

Recently, few-layer WS2, as a novel two-dimensional (2D) material, has been discovered to possess both the saturable absorption effect and the huge nonlinear refractive index. In experiment, by taking advantage of the unique optical properties of 2D WS2, we fabricated a highly nonlinear photonic device using the pulsed laser beam to deposit the WS2 film onto a fiber taper. With the WS2-based fiber taper, we have demonstrated the single- and dual-wavelength soliton pulses in the erbium-doped fiber laser (EDFL) by properly adjusting the pump strength and the polarization state. According to the soliton theory, the pulse width is $\sim 220$ fs for the single-wavelength soliton, and $\sim 585$ and $\sim 605$ fs for the dual-wavelength soliton, respectively. The dual-wavelength soliton fiber laser exhibits the maximum output power of 10.1 mW and the pulse energy of $\sim 1.14$ nJ, when the pump power is increased to $\sim 420$ mW. Our findings suggest that WS2-based fiber taper could operate as both an excellent saturable absorber for obtaining a femtosecond pulse and a promising highly nonlinear photonic material for the multi-wavelength generation.

Dual-Wavelength Soliton Mode-Locked Fiber Laser With a WS 2 -Based Fiber Taper

We reported on the generation of the dual-wavelength rectangular pulse in an erbium-doped fiber laser (EDFL) with a topological insulator saturable absorber. The rectangular pulse could be stably initiated with pulse width from 13.62 to 25.16 ns and fundamental repetition rate of 3.54 MHz by properly adjusting the pump power and the polarization state. In addition, we verified that the pulse shape of the dual-wavelength rectangular pulse can be affected by the total net cavity dispersion in the fiber laser. Furthermore, by properly rotating the polarization controllers, the harmonic mode-locking operation of the dual-wavelength rectangular pulse was also obtained. The dual-wavelength rectangular pulse EDFL would benefit some potential applications, such as spectroscopy, biomedicine, and sensing research.

Bo Guo

Papers

2D Layered Materials: Synthesis, Nonlinear Optical Properties, and Device Applications

Sub-200 fs soliton mode-locked fiber laser based on bismuthene saturable absorber

2D noncarbon materials-based nonlinear optical devices for ultrafast photonics [Invited]

Dual-Wavelength Soliton Mode-Locked Fiber Laser With a WS 2 -Based Fiber Taper

Dual-wavelength rectangular pulse erbium-doped fiber laser based on topological insulator saturable absorber