Both the nonclose-packed structure and the large refractive index contrast of guanine nanocrystals and cytosols in iridophores play a vital role in the dynamic camouflage of chameleons, including the bright skin color and color tuning sensitivity to external stimulus. Here, the nonclose-packed photonic crystals consisting of ZnS nanospheres and polymers, which have similar refractive indices with guanine nanocrystals and cytosols, respectively, are constructed by a two-step filling strategy. ZnS@SiO2 nanospheres are self-assembled to build intermediate close-packed photonic crystals followed by filling polymers in their interstices. The nonclose-packed photonic crystal is successfully achieved when the silica portion is etched by HF solution and refilled by polymers. Excitingly, the stimulus response of the designed photonic crystal is as sensitive as the skin of chameleons due to the similar contrast of refractive indices and nonclose-packed structure. The reflection peak of the structure can blue-shift more than 200 nm as the temperature increases from 30 to 55 °C or under 20% compressional strain. This work not only builds the nonclose-packed photonic crystals by introducing a two-step filling strategy but also proves that high refractive contrast in photonic crystals is an effective strategy to achieve ultrasensitivity, which is highly desirable for various applications.

Artificial Chameleon Skin with Super-Sensitive Thermal and Mechanochromic Response.

Photonic Vitrimer Elastomer with Self‐Healing, High Toughness, Mechanochromism, and Excellent Durability based on Dynamic Covalent Bond

Dynamic siloxane materials: From molecular engineering to emerging applications

A smart soft actuator with multiple capabilities of humidity-driven actuating, humidity energy harvesting, self-powered humidity sensing, and real-time motion tracking is reported. It is designed on the basis of an MXene/cellulose/polystyrene sulfonic acid (PSSA) composite membrane. This actuator is driven by asymmetric expansion under a moisture gradient during capture of the chemical potential of humidity to mechanical power. Meanwhile, the gradient moisture chemistry also induces directional proton diffusion to generate electricity with high power density and open-circuit voltage. A good linear correlation between the humidity sensitivity, electrical signal, and bending state of this actuator allows real-time tracking of motion modes with humidity change without an external power supply. This multifunctional soft actuator can be used for engineering smart switches, artificial fingers, and soft robots with trackable and distinguishable motion patterns, as well as sensitive noncontacting humidity sensor and breathing monitors.

A Ti3C2Tx MXene-Based Energy-Harvesting Soft Actuator with Self-Powered Humidity Sensing and Real-Time Motion Tracking Capability.

Extremely sensitive mechanochromic photonic crystals with broad tuning range of photonic bandgap and fast responsive speed for high-resolution multicolor display applications

Supramolecular Photonic Elastomers with Brilliant Structural Colors and Broad‐Spectrum Responsiveness

Harvesting energy from moist in the atmosphere has recently been demonstrated as an effective manner for a portable power supply to meet the ever-increasing demands of energy consumption. Porous materials are shown to have great potential in moist-induced electricity generation. Herein, we report moist-induced electricity generation by electrospun cellulose acetate (CA) membranes with optimized porous structures. We show that the pore size and porosity of CA membranes can be readily tuned via a facile compression and annealing process, and the effect of pore features on the output voltages can thus be investigated systematically. We find that, at a relatively high porosity, the electricity-generation performance can be further enhanced by constructing a smaller pore to form more nanochannels. Porous CA membranes, with an optimized porosity of 52.6% and a pore diameter less than 250 nm, are prepared to construct moist-induced electricity generators, which can be applied as breath sensors and can power up calculator operation. The current study provides insights for the construction of porous materials with different pore characteristics for moist-induced electricity generation, especially in the exploration of more efficient and low-cost porous materials for large-scale practical application of the portable power supply.

Moist-Induced Electricity Generation by Electrospun Cellulose Acetate Membranes with Optimized Porous Structures.

Organisms in nature have evolved unique structural colors and stimuli‐responsive functions for camouflage, warning, and communication over millions of years, which are essential to their survival in harsh conditions. Inspired by these characteristics, colloidal photonic composites (CPCs) composed of colloidal photonic crystals embedded in the polymeric matrix are artificially prepared and show great promise in applications. This review focuses on the summary of building blocks, i.e., colloidal particles and polymeric matrices, and constructive strategies from the perspective of designing CPCs with robust performance and specific functionality. Furthermore, their state‐of‐the‐art applications are also discussed, including colorful coatings, anti‐counterfeiting, and regulation of photoluminescence, especially in the field of visualized sensing. Finally, current challenges and potential for future developments in this field are discussed. The purpose of this review is not only to clarify the design principle for artificial CPCs but also to serve as a roadmap for the exploration of next‐generation photonic materials.

Bioinspired Colloidal Photonic Composites: Fabrications and Emerging Applications

Solar-driven steam generation has been recognized as a sustainable and low-cost solution to freshwater scarcity using abundant solar energy. To harvest freshwater, various interfacial evaporators with rational designs of photothermal materials and structures have been developed concentrating on increasing the evaporation rate in the past few years. However, pathogenic microorganism accumulation on the evaporators by long-duration contact with natural water resources may lead to the deterioration of water transportation and the reduction of the evaporation rate. Here, we develop cationic photothermal hydrogels (CPHs) based on [2-(methacryloyloxy)ethyl]trimethylammonium chloride (METAC) and photothermal polypyrrole (PPy) with bacteria-inhibiting capability for freshwater production via solar-driven steam generation. A rapid water evaporation rate of 1.592 kg m-2 h-1 under simulated solar irradiation is achieved with CPHs floating on the water surface. Furthermore, we find that CPHs possess nearly 100% antibacterial performance against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). The significant bacteria-inhibiting capability is mainly attributed to the large number of ammonium groups on the CPH network. Moreover, we show that CPHs exhibit good applicability with stable evaporation in natural lake water over 2 weeks, and the number of bacteria in purified lake water is significantly reduced. The device based on CPHs can achieve ∼0.49 kg m-2 h-1 freshwater production from lake water under natural sunlight. This study provides an attractive strategy for the evaporator to inhibit biological contamination and a potential way for long-term stable freshwater production from natural water resources in practical application.

Cationic Photothermal Hydrogels with Bacteria-Inhibiting Capability for Freshwater Production via Solar-Driven Steam Generation.

Solar steam generation provides a promising and low-cost solution for freshwater production in energy scarcity areas. However, in real-world applications, evaporators are easily affected by microorganism contamination in source water, causing surface corrosion, structural damage, or even invalidation. Developing anti-biofouling and antibacterial evaporators is significant for long-term stable freshwater production. Herein, a composite polyelectrolyte photothermal hydrogel consisting of sulfobetaine methacrylate (SBMA), [2-(methacryloyloxy)ethyl]trimethylammonium chloride (METAC), and polypyrrole (PPy) with anti-biofouling and antibacterial properties is developed. Crediting sufficient ammonium groups and zwitterionic segments, the optimized polyelectrolyte hydrogel exhibits an ∼90% antibacterial ratio against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) and effectively controls biological contamination. Under 1.0 kW m-2 solar irradiation, a rapid water evaporation rate of ∼1.690 kg m-2 h-1 and a high solar-to-evaporation efficiency of ∼95.94% are achieved with the photothermal hydrogel. We show that a lab-made setup integrated with the hydrogel can realize ∼0.455 kg m-2 h-1 freshwater production from seawater under natural sunlight. Moreover, the hydrogel exhibits excellent durability with a stable evaporation rate of ∼1.617 kg m-2 h-1 in real seawater for over 6 weeks, making it fullhearted in the real-world application of solar steam generation.

Composite Polyelectrolyte Photothermal Hydrogel with Anti-biofouling and Antibacterial Properties for the Real-World Application of Solar Steam Generation.

Bolun Peng

Papers

Supramolecular Photonic Elastomers with Brilliant Structural Colors and Broad‐Spectrum Responsiveness

Moist-Induced Electricity Generation by Electrospun Cellulose Acetate Membranes with Optimized Porous Structures.

Bioinspired Colloidal Photonic Composites: Fabrications and Emerging Applications

Cationic Photothermal Hydrogels with Bacteria-Inhibiting Capability for Freshwater Production via Solar-Driven Steam Generation.

Composite Polyelectrolyte Photothermal Hydrogel with Anti-biofouling and Antibacterial Properties for the Real-World Application of Solar Steam Generation.