Electrospinning: a fascinating fiber fabrication technique.

Electrospinning is a highly versatile method to process solutions or melts, mainly of polymers, into continuous fibers with diameters ranging from a few micrometers to a few nanometers. This technique is applicable to virtually every soluble or fusible polymer. The polymers can be chemically modified and can also be tailored with additives ranging from simple carbon-black particles to complex species such as enzymes, viruses, and bacteria. Electrospinning appears to be straightforward, but is a rather intricate process that depends on a multitude of molecular, process, and technical parameters. The method provides access to entirely new materials, which may have complex chemical structures. Electrospinning is not only a focus of intense academic investigation; the technique is already being applied in many technological areas.

Electrospinning: A Fascinating Method for the Preparation of Ultrathin Fibers

Interest in electrospinning has recently escalated due to the ability to produce materials with nanoscale properties. Electrospun fibers have been investigated as promising tissue engineering scaffolds since they mimic the nanoscale properties of native extracellular matrix. In this review, we examine electrospinning by providing a brief description of the theory behind the process, examining the effect of changing the process parameters on fiber morphology, and discussing the potential applications and impacts of electrospinning on the field of tissue engineering.

Electrospinning of polymeric nanofibers for tissue engineering applications: a review.

Although there are many methods of fabricating nanofibres, electrospinning is perhaps the most versatile process. Materials such as polymer, composites, ceramic and metal nanofibres have been fabricated using electrospinning directly or through post-spinning processes. However, what makes electrospinning different from other nanofibre fabrication processes is its ability to form various fibre assemblies. This will certainly enhance the performance of products made from nanofibres and allow application specific modifications. It is therefore vital for us to understand the various parameters and processes that allow us to fabricate the desired fibre assemblies. Fibre assemblies that can be fabricated include nonwoven fibre mesh, aligned fibre mesh, patterned fibre mesh, random three-dimensional structures and sub-micron spring and convoluted fibres. Nevertheless, more studies are required to understand and precisely control the actual mechanics in the formation of various electrospun fibrous assemblies.

https://iopscience.iop.org/article/10.1088/0957-4484/17/14/R01/pdf

A review on electrospinning design and nanofibre assemblies.

https://cyberleninka.org/article/n/1018036.pdf

Electrospun nanofibers: solving global issues

Electrospinning is a technique employed for preparing polymer fibers having diameters in the range of 10 μm–10 nm using high electrostatic field. In this letter, we report the formation of aligned polymer fibers, several centimeters in length, with separation between the fibers in the range of 5–100 μm. Achieving alignment is an important step toward the exploitation of these fibers in applications. We have employed about 4500 V and a separation distance of about 1–3 cm between the electrodes. Smaller distance between electrodes, we believe, provides better control on the formation of the fibers.

Electrospinning of continuous aligned polymer fibers

We present measurement results for the gradient of the Casimir force between an Au-coated sphere and an Au-coated plate obtained by means of an atomic force microscope operated in a frequency-shift technique. This experiment was performed at a pressure of $3\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}8}$ Torr with a hollow glass sphere of 41.3 $\ensuremath{\mu}$m radius. Special attention is paid to electrostatic calibrations, including the problem of electrostatic patches. All calibration parameters are shown to be separation independent after the corrections for mechanical drift are included. The gradient of the Casimir force was measured in two ways with applied compensating voltage to the plate and with different applied voltages and subsequent subtraction of electric forces. The obtained mean gradients are shown to be in mutual agreement and in agreement with previous experiments performed using a micromachined oscillator. The obtained data are compared with theoretical predictions of the Lifshitz theory including corrections beyond the proximity force approximation. An independent comparison with no fitting parameters demonstrated that the Drude model approach is excluded by the data at a 67$%$ confidence level over the separation region from 235 to 420 nm. The theoretical approach using the generalized plasmalike model is shown to be consistent with the data over the entire measurement range. Corrections due to the nonlinearity of oscillator are calculated and the application region of the linear regime is determined. A conclusion is made that the results of several performed experiments call for a thorough analysis of the basics of the theory of dispersion forces.

Gradient of the Casimir force between Au surfaces of a sphere and a plate measured using an atomic force microscope in a frequency-shift technique

A significant decrease in the magnitude of the Casimir force (from 21% to 35%) was observed after an indium tin oxide sample interacting with an Au sphere was subjected to the UV treatment. Measurements were performed by using an atomic force microscope in high vacuum. The experimental results are compared with theory and a hypothetical explanation for the observed phenomenon is proposed.

Reduction of the Casimir Force from Indium Tin Oxide Film by UV Treatment

We measured the gradient of the Casimir force between an Au sphere and a plate made of ferromagnetic metal (Ni). It is demonstrated that the magnetic properties influence the force magnitude. This opens prospective opportunities for the control of the Casimir force in nanotechnology and for obtaining Casimir repulsion by using ferromagnetic dielectrics.

Measurement of the gradient of the Casimir force between a nonmagnetic gold sphere and a magnetic nickel plate

We present complete results of the experiment on measuring the Casimir force between an Au-coated sphere and an untreated or, alternatively, UV-treated indium tin oxide (ITO) film deposited on a quartz substrate. Measurements were performed using an atomic force microscope in a high vacuum chamber. The measurement system was calibrated electrostatically. Special analysis of the systematic deviations is performed, and respective corrections in the calibration parameters are introduced. The corrected parameters are free from anomalies discussed in the literature. The experimental data for the Casimir force from two measurement sets for both untreated and UV-treated samples are presented. The random, systematic, and total experimental errors are determined at a 95$%$ confidence level. It is demonstrated that the UV treatment of an ITO plate results in a significant decrease in the magnitude of the Casimir force (from 21$%$ to 35$%$ depending on separation). However, ellipsometry measurements of the imaginary parts of dielectric permittivities of the untreated and UV-treated samples did not reveal any significant differences. The experimental data are compared with computations in the framework of the Lifshitz theory. It is found that the data for the untreated sample are in a very good agreement with theoretical results taking into account the free charge carriers in an ITO film. For the UV-treated sample the data exclude the theoretical results obtained with account of free charge carriers. These data are in very good agreement with computations disregarding the contribution of free carriers in the dielectric permittivity. According to the hypothetical explanation provided, this is caused by the phase transition of the ITO film from metallic to dielectric state caused by the UV treatment. Possible applications of the discovered phenomenon in nanotechnology are discussed.

C.-C. Chang

Papers

Electrospinning of continuous aligned polymer fibers

Gradient of the Casimir force between Au surfaces of a sphere and a plate measured using an atomic force microscope in a frequency-shift technique

Reduction of the Casimir Force from Indium Tin Oxide Film by UV Treatment

Measurement of the gradient of the Casimir force between a nonmagnetic gold sphere and a magnetic nickel plate

Modifying the Casimir force between indium tin oxide film and Au sphere