C
Cameron J. Kepert
Researcher at University of Sydney
Publications - 202
Citations - 13826
Cameron J. Kepert is an academic researcher from University of Sydney. The author has contributed to research in topics: Spin crossover & Negative thermal expansion. The author has an hindex of 59, co-authored 197 publications receiving 12769 citations. Previous affiliations of Cameron J. Kepert include University of Cambridge & University of Queensland.
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Guest-Dependent Spin Crossover in a Nanoporous Molecular Framework Material
TL;DR: The generation of a host lattice that interacts with exchangeable guest species in a switchable fashion has implications for the generation of previously undeveloped advanced materials with applications in areas such as molecular sensing.
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A Versatile Family of Interconvertible Microporous Chiral Molecular Frameworks: The First Example of Ligand Control of Network Chirality
TL;DR: In this paper, two families of molecular frameworks which grow as homochiral single crystals are described, which consist of multiple interpenetration of the three-connected chiral (10,3)-a (Y*) network and result from the tridentate coordination of the 1,3,5-benzenetricarboxylate (btc) ligand to octahedral metal centers.
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Advanced functional properties in nanoporous coordination framework materials
TL;DR: A number of areas where specific function has been incorporated into framework host lattices for their extreme chemical versatility are highlighted.
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Dynamic interplay between spin-crossover and host-guest function in a nanoporous metal-organic framework material.
Peter D. Southon,Lang Liu,Elizabeth A. Fellows,David J. Price,Gregory J. Halder,Karena W. Chapman,Boujemaa Moubaraki,Keith S. Murray,Jean-François Létard,Cameron J. Kepert +9 more
TL;DR: Through the comprehensive analysis of structure, host-guest properties, and spin-crossover behaviors, it is found that this pillared Hofmann system uniquely displays both guest-exchange-induced changes to spin- crossovers and spinsorption and desorption changes to host- Guernsey properties, with direct dynamic interplay between these two phenomena.
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Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials
TL;DR: In this paper, the intrinsic geometric flexibility of framework structures incorporating linear metal-cyanide-consuming linkages using a reciprocal-space dynamical matrix approach was analyzed, and it was shown that this structural motif is capable of imparting a significant negative thermal expansion sNTEd effect upon such materials.