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Carmine Capacchione
Researcher at University of Salerno
Publications - 107
Citations - 2625
Carmine Capacchione is an academic researcher from University of Salerno. The author has contributed to research in topics: Catalysis & Polymerization. The author has an hindex of 27, co-authored 95 publications receiving 2152 citations. Previous affiliations of Carmine Capacchione include University of Mainz & Heidelberg University.
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Journal ArticleDOI
Ancillary ligand effect on single-site styrene polymerization: isospecificity of group 4 metal bis(phenolate) catalysts.
Carmine Capacchione,Antonio Proto,Henner Ebeling,Rolf Mülhaupt,Klaus Möller,Thomas P. Spaniol,Jun Okuda +6 more
TL;DR: Styrene is polymerized isospecifically by group 4 metal complexes that contain a C2-symmetrically coordinated 1,4-dithiabutane-linked bis(phenolato) ligand activated by methylaluminoxane.
Journal ArticleDOI
Isospecific Styrene Polymerization by Chiral Titanium Complexes That Contain a Tetradentate [OSSO]-Type Bis(phenolato) Ligand
Carmine Capacchione,Ramanujachary Manivannan,Marco Barone,Klaus Beckerle,Roberto Centore,Leone Oliva,Antonio Proto,Angela Tuzi,and Thomas P. Spaniol,Jun Okuda +9 more
TL;DR: A series of titanium dichloro and di(isopropoxy) complexes with a 1,4-dithiabutanediyl-linked bis(4,6-disubstituted phenolato) ligand were synthesized by reacting the corresponding linked bis(phenol) (HOC6H2-6-R1-4-R2)2{S(CH2)-2S} (1a−i) with the titanium precursor TiX4 as mentioned in this paper.
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Novel iron(III) catalyst for the efficient and selective coupling of carbon dioxide and epoxides to form cyclic carbonates
Antonio Buonerba,Assunta De Nisi,Alfonso Grassi,Stefano Milione,Carmine Capacchione,Sergei I. Vagin,Bernhard Rieger +6 more
TL;DR: In this article, the synthesis of cyclic organic carbonates in high yield, stereo-and chemo-selectivity was accomplished through the coupling of carbon dioxide and epoxides, catalysed by a novel air-stable and easy-to-handle thioether-triphenolate iron(III) complex.
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[OSSO]-Type Iron(III) Complexes for the Low-Pressure Reaction of Carbon Dioxide with Epoxides: Catalytic Activity, Reaction Kinetics, and Computational Study
Francesco Della Monica,Bholanath Maity,Thomas M. Pehl,Antonio Buonerba,Assunta De Nisi,Magda Monari,Alfonso Grassi,Bernhard Rieger,Luigi Cavallo,Carmine Capacchione +9 more
TL;DR: In this paper, the selective conversion of various substituted epoxides into the corresponding cyclic carbonates under mild reaction conditions was achieved with mononuclear Fe(III) complexes bearing bis-thioether-diphenolate [OSSO]-type ligands, in combination with tetrabutylammonium bromide (TBAB).
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Stereoselective Polymerization of Conjugated Dienes and Styrene−Butadiene Copolymerization Promoted by Octahedral Titanium Catalyst
Stefano Milione,Cinzia Cuomo,Carmine Capacchione,Carla Zannoni,and Alfonso Grassi,Antonio Proto +5 more
TL;DR: In this article, the ability of the dichloro{1,4-dithiabutanediyl-2,2‘-bis(4,6-di-tert-butylphenoxy)}titanium complex to catalyze homopolymerization of conjugated dienes and copolymerisation of butadiene with styrene is reported.