A topical review of numerical and experimental studies of supercontinuum generation in photonic crystal fiber is presented over the full range of experimentally reported parameters, from the femtosecond to the continuous-wave regime. Results from numerical simulations are used to discuss the temporal and spectral characteristics of the supercontinuum, and to interpret the physics of the underlying spectral broadening processes. Particular attention is given to the case of supercontinuum generation seeded by femtosecond pulses in the anomalous group velocity dispersion regime of photonic crystal fiber, where the processes of soliton fission, stimulated Raman scattering, and dispersive wave generation are reviewed in detail. The corresponding intensity and phase stability properties of the supercontinuum spectra generated under different conditions are also discussed.

Supercontinuum generation in photonic crystal fiber

The rise time of intense radiation determines the maximum field strength atoms can be exposed to before their polarizability dramatically drops due to the detachment of an outer electron. Recent progress in ultrafast optics has allowed the generation of ultraintense light pulses comprising merely a few field oscillation cycles. The arising intensity gradient allows electrons to survive in their bound atomic state up to external field strengths many times higher than the binding Coulomb field and gives rise to ionization rates comparable to the light frequency, resulting in a significant extension of the frontiers of nonlinear optics and (nonrelativistic) high-field physics. Implications include the generation of coherent harmonic radiation up to kiloelectronvolt photon energies and control of the atomic dipole moment on a subfemtosecond $(1{\mathrm{f}\mathrm{s}=10}^{\mathrm{\ensuremath{-}}15}\mathrm{}\mathrm{s})$ time scale. This review presents the landmarks of the 30-odd-year evolution of ultrashort-pulse laser physics and technology culminating in the generation of intense few-cycle light pulses and discusses the impact of these pulses on high-field physics. Particular emphasis is placed on high-order harmonic emission and single subfemtosecond extreme ultraviolet/x-ray pulse generation. These as well as other strong-field processes are governed directly by the electric-field evolution, and hence their full control requires access to the (absolute) phase of the light carrier. We shall discuss routes to its determination and control, which will, for the first time, allow access to the electromagnetic fields in light waves and control of high-field interactions with never-before-achieved precision.

Intense few-cycle laser fields: Frontiers of nonlinear optics

Femtosecond filamentation in transparent media

Optical second-harmonic generation and the related technique of infrared – visible light sum-frequency generation are extremely versatile tools for studies of many kinds of surfaces and interfaces. With the help of ultra-short laser pulses, they can be used to monitor surface dynamics and reactions with sub-picosecond time resolution.

Surface properties probed by second-harmonic and sum-frequency generation

4. Survey of Novel Multiphoton Active Materials 1257 4.1. Multiphoton Absorbing Systems 1257 4.2. Organic Molecules 1257 4.3. Organic Liquids and Liquid Crystals 1259 4.4. Conjugated Polymers 1259 4.4.1. Polydiacetylenes 1261 4.4.2. Polyphenylenevinylenes (PPVs) 1261 4.4.3. Polythiophenes 1263 4.4.4. Other Conjugated Polymers 1265 4.4.5. Dendrimers 1265 4.4.6. Hyperbranched Polymers 1267 4.5. Fullerenes 1267 4.6. Coordination and Organometallic Compounds 1271 4.6.1. Metal Dithiolenes 1271 4.6.2. Pyridine-Based Multidentate Ligands 1272 4.6.3. Other Transition-Metal Complexes 1273 4.6.4. Lanthanide Complexes 1275 4.6.5. Ferrocene Derivatives 1275 4.6.6. Alkynylruthenium Complexes 1279 4.6.7. Platinum Acetylides 1279 4.7. Porphyrins and Metallophophyrins 1279 4.8. Nanoparticles 1281 4.9. Biomolecules and Derivatives 1282 5. Nonlinear Optical Characterizations of Multiphoton Active Materials 1282

Multiphoton Absorbing Materials : Molecular Designs, Characterizations, and Applications

The reflectivity of silicon has been measured following excitation with intense 90-fsec optical pulses. These measurements for the first time clearly resolve in time the process of energy transfer to the crystal lattice and the dynamics of the phase transition to the melted state.

Time-Resolved Reflectivity Measurements of Femtosecond-Optical-Pulse-Induced Phase Transitions in Silicon

We obtain gigawatt white-light continuum pulses that permit spectroscopic measurements with a time resolution of 80 fsec. These pulses extend continuously from 0.19 to 1.6 μm and have time sweeps as small as 10 fsec/1000 A. We find temporal, spatial, and spectral properties that are consistent with self-phase modulation having a prominent role in generation of the continuum.

Femtosecond white-light continuum pulses.

We report the first direct observation of nonthermal photoexcited carrier distributions in GaAs quantum-well structures. We present experimental studies which show that these distributions thermalize within 200 fs. In addition we are able to show that near the band edge the effect of long-range Coulomb screening on the bleaching of the two-dimensional-exciton resonances is much weaker than that of the Pauli exclusion principle.

Femtosecond excitation of nonthermal carrier populations in GaAs quantum wells.

The dynamics of the structural changes that take place on a silicon surface following excitation with an intense optical pulse are observed with 90-fs time resolution. The threefold rotational symmetry of the silicon $〈111〉$ surface becomes rotationally isotropic within a picosecond after excitation consistent with a transition from the crystalline to the liquid molten state.

Femtosecond-Time-Resolved Surface Structural Dynamics of Optically Excited Silicon

We report direct measurements of the frequency dependence of the optical group delay for a number of optical components commonly used in femtosecond optics. We have investigated the group-delay errors that occur on reflection from metal and dielectric mirrors under various conditions and passage through devices that introduce angular dispersion. We obtain measurement accuracy of about ±1 fsec over the spectral range of 400–750 nm.

Charles Hirlimann

Papers

Time-Resolved Reflectivity Measurements of Femtosecond-Optical-Pulse-Induced Phase Transitions in Silicon

Femtosecond white-light continuum pulses.

Femtosecond excitation of nonthermal carrier populations in GaAs quantum wells.

Femtosecond-Time-Resolved Surface Structural Dynamics of Optically Excited Silicon

Interferometric measurements of femtosecond group delay in optical components