https://ir.nctu.edu.tw:443/bitstream/11536/14909/1/000297489400002.pdf

POSS related polymer nanocomposites

该文章系统总结了自1912年发现Breath Figure现象，直至近年来以此方法制备有序多孔聚合物膜及其应用的相关文献逾550篇。
李磊教授自2007年回国成立课题组以来，一直致力于多孔材料新型制备方法学研究及应用，独立发展和完善了静态Breath Figure制备方法。

Breath Figure: A Nature-Inspired Preparation Method for Ordered Porous Films

Polymer–drug compatibility: A guide to the development of delivery systems for the anticancer agent, ellipticine

Rod–coil block copolymers are an increasingly important class of molecules for the self-assembly of functional polymer systems, many of which have rodlike chain conformations due to rigid secondary structures, extended π-conjugation, or aromatic groups along the polymer backbone. Examples of these polymers are helical proteins, polyisocyanates, main-chain semiconducting polymers, and aromatic polyesters, polyamides, or polyimines. Many hindered or liquid crystalline systems self-assembled from block copolymers, including dendronized polymers and mesogen-jacketed liquid crystalline polymers, also form rod–coil block copolymers. In these cases, steric crowding of the bulky or mesogenic side chains causes the polymer backbone to become quasi-linear. The incorporation of rigid rod polymers into the block copolymers results in extremely rich self-assembly behavior that differs markedly from that of traditional block copolymers due to the interplay between microphase separation of the rod and coil components and liquid crystalline alignment. The combination of these effects results in novel structures both in solution and melts. This review discusses in detail the self-assembly and thermodynamics of rod–coil diblock and triblock copolymers. After summarizing the applications of these materials, their aggregation and gelation in solution is discussed. Our knowledge of their bulk phase behavior is thoroughly reviewed both from the experimental and theoretical perspectives, and the self-assembly of these materials in thin film geometries that are critical to many applications in organic electronics and functional surface patterning is treated. Finally, the outlook for the future of these systems is summarized along with current knowledge gaps and exciting areas for the advancement of the field.

Self-assembly of rod–coil block copolymers

Modification of epoxy resins with functional silanes, polysiloxanes, silsesquioxanes, silica and silicates

The phase behavior and hydrogen bonding in ternary polymer blends of phenolic resin, poly(ethylene oxide) (PEO), and poly(e-caprolactone) (PCL) were investigated by using differential scanning calorimetry (DSC) and Fourier transform infrared spectroscopy (FTIR). Although all three binary blends are respective miscible, there exists a closed immiscibility loop in the phase diagram due to the so-called “Δχ” and “ΔK” effects in this hydrogen-bonded ternary polymer system. The interassociation equilibrium constant based on the Painter−Coleman association model between phenolic resin and PEO can be indirectly calculated from the fraction of hydrogen-bonded carbonyl groups. Quantitative analyses show that the hydroxyl−ether interassociation is more favorable than the hydroxyl−carbonyl interassociation at room temperature. The interaction energy density value of BPEO/PCL= −2.85 cal/cm3 was obtained by comparing the theoretically predicted phase diagram with experimental data.

https://ir.nctu.edu.tw:443/bitstream/11536/29097/1/000173023200037.pdf

Phase Behavior and Hydrogen Bonding in Ternary Polymer Blends of Phenolic Resin/Poly(ethylene oxide)/Poly(ε-caprolactone)

https://ir.nctu.edu.tw:443/bitstream/11536/28741/1/000176030500012.pdf

The study of hydrogen bonding and miscibility in poly(vinylpyridines) with phenolic resin

A series of poly(vinylphenol-co-methyl methacrylate) (PVPh-co-PMMA) block and random copolymers were prepared through anionic and free radical polymerizations, respectively, of 4-tert-butoxystyrene and methyl methacrylate and subsequent selective hydrolysis of the 4-tert-butoxystyrene protective groups. Analysis of infrared spectra suggests that the random copolymer possesses a higher fraction of hydrogen-bonded carbonyl groups and a larger interassociation equilibrium constant relative to those of a block copolymer containing similar vinylphenol content because of the different sequence distribution that may arise from the so-called intramolecular screening effect. In contrast, the glass transition temperature of the block copolymer, which has the lower polydispersity index, is higher than that of the random copolymer at the same composition.

https://ir.nctu.edu.tw:443/bitstream/11536/13470/1/000230627000030.pdf

Sequence Distribution and Polydispersity Index Affect the Hydrogen-Bonding Strength of Poly(vinylphenol-co-methyl methacrylate) Copolymers

https://ir.nctu.edu.tw:443/bitstream/11536/10791/1/000246934600019.pdf

Micellar morphologies of self-associated diblock copolymers in acetone solution

A nanoporous additives, polyhedral oilgomeric silisesquioxane containing eight functional hexafluorine groups, octakis(dimethylsiloxyhexafluoropropyl ether)- silsesquioxane (OF) has been synthesized and blended with the UV-cured epoxy resin. The OF containing (10%) epoxy has significantly lower dielectric constant (2.65) than the plain epoxy (3.71). The incorporation of fluorine containing additives is well- known to reduce dielectric constant due to lower its polarizability. In addition, the presence of the bulky POSS structure is able to create additional free space or pores and further reduces the dielectric constant of the epoxy matrix. V

https://ir.nctu.edu.tw:443/bitstream/11536/11127/1/000244012800012.pdf

Chen-Lung Lin

Papers

Phase Behavior and Hydrogen Bonding in Ternary Polymer Blends of Phenolic Resin/Poly(ethylene oxide)/Poly(ε-caprolactone)

The study of hydrogen bonding and miscibility in poly(vinylpyridines) with phenolic resin

Sequence Distribution and Polydispersity Index Affect the Hydrogen-Bonding Strength of Poly(vinylphenol-co-methyl methacrylate) Copolymers

Micellar morphologies of self-associated diblock copolymers in acetone solution

Novel epoxy nanocomposite of low Dk introduced fluorine‐containing POSS structure