Some Preliminary Thoughts * Part I: Inviscid Hypersonic Flow * Hypersonic Shock and Expansion-Wave Relations * Local Surface Inclination Methods * Hypersonic Inviscid Flowfields: Approximate Methods * Hypersonic Inviscid Flowfields: Exact Methods * Part II: Viscous Hypersonic Flow * Viscous Flow: Basic Aspects, Boundary Layer Results, and Aerodynamic Heating * Hypersonic Viscous Interactions * Computational Fluid Dynamic Solutions of Hypersonic Viscous Flows * Part III: High-Temperature Gas Dynamics * High-Temperature Gas Dynamics: Some Introductory Considerations * Some Aspects of the Thermodynamics of Chemically Reacting Gases (Classical Physical Chemistry) * Elements of Statistical Thermodynamics * Elements of Kinetic Theory * Chemical Vibrational Nonequilibrium * Inviscid High-Temperature Equilibrium Flows * Inviscid High-Temperature Nonequilibrium Flows * Kinetic Theory Revisited: Transport Properties in High-Temperature Gases * Viscous High-Temperature Flows * Introduction to Radiative Gas Dynamics.

Hypersonic and high temperature gas dynamics

A number of chemical-kinetic problems related to phenomena occurring behind a shock wave surrounding an object flying in the earth atmosphere are discussed, including the nonequilibrium thermochemical relaxation phenomena occurring behind a shock wave surrounding the flying object, problems related to aerobraking maneuver, the radiation phenomena for shock velocities of up to 12 km/sec, and the determination of rate coefficients for ionization reactions and associated electron-impact ionization reactions. Results of experiments are presented in form of graphs and tables, giving data on the reaction rate coefficients for air, the ionization distances, thermodynamic properties behind a shock wave, radiative heat flux calculations, Damkoehler numbers for the ablation-product layer, together with conclusions.

Review of chemical-kinetic problems of future NASA missions, II: Mars entries

In recent decades particular interest in applications of nonequilibrium plasma for the problems of plasma-assisted ignition and plasma-assisted combustion has been observed. A great amount of experimental data has been accumulated during this period which provided the grounds for using low temperature plasma of nonequilibrium gas discharges for a number of applications at conditions of high speed flows and also at conditions similar to automotive engines. The paper is aimed at reviewing the data obtained and discusses their treatment. Basic possibilities of low temperature plasma to ignite gas mixtures are evaluated and historical references highlighting pioneering works in the area are presented. The first part of the review discusses plasmas applied to plasma-assisted ignition and combustion. The paper pays special attention to experimental and theoretical analysis of some plasma parameters, such as reduced electric field, electron density and energy branching for different gas discharges. Streamers, pulsed nanosecond discharges, dielectric barrier discharges, radio frequency discharges and atmospheric pressure glow discharges are considered. The second part depicts applications of discharges to reduce the ignition delay time of combustible mixtures, to ignite transonic and supersonic flows, to intensify ignition and to sustain combustion of lean mixtures. The results obtained by different authors are cited, and ways of numerical modelling are discussed. Finally, the paper draws some conclusions on the main achievements and prospects of future investigations in the field.

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Plasma assisted ignition and combustion

This work is an overview of available theories and finite elements that have been developed for multilayered, anisotropic, composite plate and shell structures. Although a comprehensive description of several techniques and approaches is given, most of this paper has been devoted to the so called axiomatic theories and related finite element implementations. Most of the theories and finite elements that have been proposed over the last thirty years are in fact based on these types of approaches. The paper has been divided into three parts. Part I, has been devoted to the description of possible approaches to plate and shell structures: 3D approaches, continuum based methods, axiomatic and asymptotic two-dimensional theories, classical and mixed formulations, equivalent single layer and layer wise variable descriptions are considered (the number of the unknown variables is considered to be independent of the number of the constitutive layers in the equivalent single layer case). Complicating effects that have been introduced by anisotropic behavior and layered constructions, such as high transverse deformability, zig-zag effects and interlaminar continuity, have been discussed and summarized by the acronimC
 -Requirements. Two-dimensional theories have been dealt with in Part II. Contributions based on axiomatic, asymtotic and continuum based approaches have been overviewed. Classical theories and their refinements are first considered. Both case of equivalent single-layer and layer-wise variables descriptions are discussed. The so-called zig-zag theories are then discussed. A complete and detailed overview has been conducted for this type of theory which relies on an approach that is entirely originated and devoted to layered constructions. Formulas and contributions related to the three possible zig-zag approaches, i.e. Lekhnitskii-Ren, Ambartsumian-Whitney-Rath-Das, Reissner-Murakami-Carrera ones have been presented and overviewed, taking into account the findings of a recent historical note provided by the author. Finite Element FE implementations are examined in Part III. The possible developments of finite elements for layered plates and shells are first outlined. FEs based on the theories considered in Part II are discussed along with those approaches which consist of a specific application of finite element techniques, such as hybrid methods and so-called global/local techniques. The extension of finite elements that were originally developed for isotropic one layered structures to multilayerd plates and shells are first discussed. Works based on classical and refined theories as well as on equivalent single layer and layer-wise descriptions have been overviewed. Development of available zig-zag finite elements has been considered for the three cases of zig-zag theories. Finite elements based on other approches are also discussed. Among these, FEs based on asymtotic theories, degenerate continuum approaches, stress resultant methods, asymtotic methods, hierarchy-p,_-s global/local techniques as well as mixed and hybrid formulations have been overviewed.

Theories and Finite Elements for Multilayered, Anisotropic, Composite Plates and Shells

Plasma-assisted ignition and combustion

Nonequilibrium phenomena in hypersonic flows are examined on the basis of theoretical models and selected experimental data, in an introduction intended for second-year graduate students of aerospace engineering. Chapters are devoted to the physical nature of gas atoms and molecules, transitions of internal states, the formulation of the master equation of aerothermodynamics, the conservation equations, chemical reactions in CFD, the behavior of air flows in nonequilibrium, experimental aspects of nonequilibrium flow, a review of experimental results, and gas-solid interaction. Diagrams, graphs, and tables of numerical data are provided.

Nonequilibrium hypersonic aerothermodynamics

A two-temperatur e chemical-kinet ic model for air is assessed by comparing theoretical results with existing experimental data obtained in shock tubes, ballistic ranges, and flight experiments. In the model, one temperature (T) is assumed to characterize the heavy-particle translational and molecular rotational energies, and another temperature (Tv) the molecular vibrational, electron translational, and electronic excitation energies. The theoretical results for nonequilibrium flow in shock tubes are obtained using the computer code STRAP (shock-tube radiation program) and for flow along the stagnation streamline in the shock layer over spherical bodies using the newly developed code SPRAP (stagnation-point radiation program). Substantial agreement is shown between the theoretical and experimental results for relaxation times and radiative heat fluxes. At very high temperatures, the spectral calculations need further improvement. The present agreement provides strong evidence that the two-temperature model characterizes principal features of nonequilibriu m airflow. New theoretical results using the model are presented for the radiative heat fluxes at the stagnation point of 6 m radius sphere, representing an aeroassisted orbital transfer vehicle, over a range of freestream conditions. Assumptions, approximations, and limitations of the model are discussed. Nomenclature = average molecular speed ^/$kT/nm, cm s ~ ! = pre-exponential factor in reaction rate coefficient, cm3mole~ 1 s~ * - average vibrational energy per particle, erg = average vibrational energy per particle under equilibrium, erg = reaction energy, erg

Assessment of two-temperature kinetic model for ionizing air

The validity of the author's two-temperature, chemical/kinetic model which the author has recently improved is assessed by comparing the calculated results with the existing experimental data for nitrogen in the dissociating and weakly ionizing regime produced behind a normal shock wave. The computer program Shock Tube Radiation Program (STRAP) based on the two-temperature model is used in calculating the flow properties behind the shock wave and the Nonequilibrium Air Radiation (NEQAIR) program, in determining the radiative characteristics of the flow. Both programs were developed earlier. Comparison is made between the calculated and the existing shock tube data on (1) spectra in the equilibrium region, (2) rotational temperature of the N2(+) B state, (3) vibrational temperature of the N2(+) B state, (4) electronic excitation temperature of the N2 B state, (5) the shape of time-variation of radiation intensities, (6) the times to reach the peak in radiation intensity and equilibrium, and (7) the ratio of nonequilibrium to equilibrium radiative heat fluxes. Good agreement is seen between the experimental data and the present calculation except for the vibrational temperature. A possible reason for the discrepancy is given.

Assessment of a two-temperature kinetic model for dissociating and weakly ionizing nitrogen

This document is the User's Manual for a new version of the NEQAIR computer program, NEQAIR96. The program is a line-by-line and a line-of-sight code. It calculates the emission and absorption spectra for atomic and diatomic molecules and the transport of radiation through a nonuniform gas mixture to a surface. The program has been rewritten to make it easy to use, run faster, and include many run-time options that tailor a calculation to the user's requirements. The accuracy and capability have also been improved by including the rotational Hamiltonian matrix formalism for calculating rotational energy levels and Hoenl-London factors for dipole and spin-allowed singlet, doublet, triplet, and quartet transitions. Three sample cases are also included to help the user become familiar with the steps taken to produce a spectrum. A new user interface is included that uses check location, to select run-time options and to enter selected run data, making NEQAIR96 easier to use than the older versions of the code. The ease of its use and the speed of its algorithms make NEQAIR96 a valuable educational code as well as a practical spectroscopic prediction and diagnostic code.

https://ntrs.nasa.gov/api/citations/19970004690/downloads/19970004690.pdf

Chul Park

Papers

Nonequilibrium hypersonic aerothermodynamics

Review of chemical-kinetic problems of future NASA missions, II: Mars entries

Assessment of two-temperature kinetic model for ionizing air

Assessment of a two-temperature kinetic model for dissociating and weakly ionizing nitrogen

NEQAIR96,Nonequilibrium and Equilibrium Radiative Transport and Spectra Program: User's Manual