Preface.- Contributors.- List of Abbreviations.- Section 1: Basic Principles: Introduction.-Sources of Heavy Metals and Metalloids in Soils.- Chemistry of Heavy Metals and Metalloids in Soils.- Methods for the Determination of Heavy Metals and Metalloids in Soils.- Effects of Heavy Metals and Metalloids on Soil Organisms.- Soil-Plant Relationships of Heavy Metals and Metalloids.- Heavy Metals and Metalloids as Micronutrients for Plants and Animals.-Critical Loads of Heavy Metals for Soils.- Section 2: Key Heavy Metals And Metalloids: Arsenic.- Cadmium.- Chromium and Nickel.- Cobalt and Manganese.- Copper.-Lead.- Mercury.- Selenium.- Zinc.- Section 3: Other Heavy Metals And Metalloids Of Potential Environmental Significance: Antimony.- Barium.- Gold.- Molybdenum.- Silver.- Thallium.- Tin.- Tungsten.- Uranium.- Vanadium.- Glossary of Specialized Terms.- Index.

Heavy metals in soils : trace metals and metalloids in soils and their bioavailability

Zircon and rutile are common accessory minerals whose essential structural constituents, Zr, Ti, and Si can replace one another to a limited extent. Here we present the combined results of high pressure–temperature experiments and analyses of natural zircons and rutile crystals that reveal systematic changes with temperature in the uptake of Ti in zircon and Zr in rutile. Detailed calibrations of the temperature dependencies are presented as two geothermometers—Ti content of zircon and Zr content of rutile—that may find wide application in crustal petrology. Synthetic zircons were crystallized in the presence of rutile at 1–2 GPa and 1,025–1,450°C from both silicate melts and hydrothermal solutions, and the resulting crystals were analyzed for Ti by electron microprobe (EMP). To augment and extend the experimental results, zircons hosted by five natural rocks of well-constrained but diverse origin (0.7–3 GPa; 580–1,070°C) were analyzed for Ti, in most cases by ion microprobe (IMP). The combined experimental and natural results define a log-linear dependence of equilibrium Ti content (expressed in ppm by weight) upon reciprocal temperature:

 $$\log ({\text{Ti}}_{{{\text{zircon}}}}) = (6.01 \pm 0.03) - \frac{{5080 \pm 30}}{{T\;(\hbox{K})}}.$$
 In a strategy similar to that used for zircon, rutile crystals were grown in the presence of zircon and quartz (or hydrous silicic melt) at 1–1.4 GPa and 675–1,450°C and analyzed for Zr by EMP. The experimental results were complemented by EMP analyses of rutile grains from six natural rocks of diverse origin spanning 0.35–3 GPa and 470–1,070°C. The concentration of Zr (ppm by weight) in the synthetic and natural rutiles also varies in log-linear fashion with T
 −1:

 $$\log ({\text{Zr}}_{{{\text{rutile}}}}) = (7.36 \pm 0.10) - \frac{{4470 \pm 120}}{{T\;(\hbox{K})}}.$$
 The zircon and rutile calibrations are consistent with one another across both the synthetic and natural samples, and are relatively insensitive to changes in pressure, particularly in the case of Ti in zircon. Applied to natural zircons and rutiles of unknown provenance and/or growth conditions, the thermometers have the potential to return temperatures with an estimated uncertainty of ±10 ° or better in the case of zircon and ±20° or better in the case of rutile over most of the temperature range of interest (∼400–1,000°C). Estimates of relative temperature or changes in temperature (e.g., from zoning profiles in a single mineral grain) made with these thermometers are subject to analytical uncertainty only, which can be better than ±5° depending on Ti or Zr concentration (i.e., temperature), and also upon the analytical instrument (e.g., IMP or EMP) and operating conditions.

Crystallization thermometers for zircon and rutile

The flow of homogeneous fluids through porous media: analogies with other physical problems

Responding to the latest developments in rock physics research, this popular reference book has been thoroughly updated while retaining its comprehensive coverage of the fundamental theory, concepts, and laboratory results. It brings together the vast literature from the field to address the relationships between geophysical observations and the underlying physical properties of Earth materials - including water, hydrocarbons, gases, minerals, rocks, ice, magma and methane hydrates. This third edition includes expanded coverage of topics such as effective medium models, viscoelasticity, attenuation, anisotropy, electrical-elastic cross relations, and highlights applications in unconventional reservoirs. Appendices have been enhanced with new materials and properties, while worked examples (supplemented by online datasets and MATLAB® codes) enable readers to implement the workflows and models in practice. This significantly revised edition will continue to be the go-to reference for students and researchers interested in rock physics, near-surface geophysics, seismology, and professionals in the oil and gas industries.

The Rock Physics Handbook

SUMMARY The phase relationships contained in the magnetotelluric (MT) impedance tensor are shown to be a second-rank tensor. This tensor expresses how the phase relationships change with polarization in the general case where the conductivity structure is 3-D. Where galvanic effects produced by heterogeneities in near-surface conductivity distort the regional MT response the phase tensor preserves the regional phase information. Calculation of the phase tensor requires no assumption about the dimensionality of the underlying conductivity distribution and is applicable where both the heterogeneity and regional structure are 3-D. For 1-D regional conductivity structures, the phase tensor is characterized by a single coordinate invariant phase equal to the 1-D impedance tensor phase. If the regional conductivity structure is 2-D, the phase tensor is symmetric with one of its principal axes aligned parallel to the strike axis of the regional structure. In the 2-D case, the principal values (coordinate invariants) of the phase tensor are the transverse electric and magnetic polarization phases. The orientation of the phase tensor’s principal axes can be determined directly from the impedance tensor components in both 2-D and 3-D situations. In the 3-D case, the phase tensor is nonsymmetric and has a third coordinate invariant that is a distortion-free measure of the asymmetry of the regional MT response. The phase tensor can be depicted graphically as an ellipse, the major and minor axes representing the principal axes of the tensor. 3-D model studies show that the orientations of the phase tensor principal axes reflect lateral variations (gradients) in the underlying regional conductivity structure. Maps of the phase tensor ellipses provide a method of visualizing this variation.

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The magnetotelluric phase tensor

The Taupo Volcanic Zone (TVZ) in the central North Island of New Zealand lies across the boundary formed in the late Mesozoic between two major basement regions: the Waipapa and Torlesse composite terranes. However, the precise location of this terrane contact within the TVZ is not well constrained because it is buried beneath Pleistocene volcanic and volcaniclastic sequences locally >3 km thick. Here we report new U-Pb zircon detrital age spectra from basement sandstones and younger Waikora Formation greywacke gravel from five geothermal well core samples and one surface sample. We combine these new data with existing TVZ zircon xenocryst and xenolith age spectra from volcanic host rocks, to correlate these materials with each basement terrane and constrain the likely spatial location and uncertainty of the terrane boundary under the TVZ. Its position with respect to surficial geothermal systems suggests that, at depth, the terrane boundary may have been reactivated by Quaternary extension in the evolving Taupo Rift. Put another way, the past and current position of the Taupo Rift fundamentally may have been controlled by the terrane boundary, which may ultimately be partly responsible for providing enhanced fracture permeability for deep-seated geothermal fluids.

The Mesozoic terrane boundary beneath the Taupo Volcanic Zone, New Zealand, and potential controls on geothermal system characteristics

We use crustal seismic anisotropy measurements in the North Island, New Zealand, to examine structures and stress within the Taupō Volcanic Zone, the Taranaki Volcanic Lineament, the subducting Hikurangi slab, and the Hikurangi forearc. Results in the Taranaki region are consistent with NW-SE oriented extension yet suggest that the Taranaki volcanic lineament may be controlled by a deep-rooted, inherited crustal structure. In the central Taupō Volcanic Zone anisotropy fast orientations are predominantly controlled by continental rifting. However at Taupō and Okataina volcanoes, fast orientations are highly variable and radial to the calderas suggesting the influence of magma reservoirs in the seismogenic crust (≤15 km depth). The subducting Hikurangi slab has a predominant trench-parallel fast orientation, reflecting the pervasive presence of plate-bending faults, yet changing orientations at depths ≥120 km beneath the central North Island may be relics from previous subduction configurations. Finally, results from the southern Hikurangi forearc show that the orientation of stresses there is consistent with those in the underlying subducting slab. In contrast, the northern Hikurangi forearc is pervasively fractured and is undergoing E-W compression, oblique to the stress field in the subducting slab. The north-south variation in fore-arc stress is likely related to differing subduction-interface coupling. Across the varying tectonic regimes of the North Island our study highlights that large-scale tectonic forces tend to dictate the orientation of stress and structures within the crust, although more localized features (plate coupling, magma reservoirs, and inherited crustal structures) can strongly influence surface magmatism and the crustal stress field.

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Mapping Stress and Structure From Subducting Slab to Magmatic Rift: Crustal Seismic Anisotropy of the North Island, New Zealand

Department of Conservation, New Zealand (DOCDM-593774); Victoria University of Wellington (DVC Research Grant 13311); Japan Society for the Promotion of Science (Postdoctoral Research Fellowship JSPS P16788)

Colin J. N. Wilson

Papers

The Mesozoic terrane boundary beneath the Taupo Volcanic Zone, New Zealand, and potential controls on geothermal system characteristics

Mapping Stress and Structure From Subducting Slab to Magmatic Rift: Crustal Seismic Anisotropy of the North Island, New Zealand

New petrological, geochemical, and geochronological perspectives on andesite-dacite magma genesis at Ruapehu volcano, New Zealand

Os isotopic constraints on crustal contamination in Auckland Volcanic Field basalts, New Zealand

Strombolian deposits at Mayor Island; basaltic eruption styles displayed by a peralkaline rhyolitic volcano