On the microstructural characteristics influencing the yielding behavior of ultra-fine grained medium-Mn steels

This is a viewpoint paper on recent progress in the understanding of the microstructure–property relations of advanced high-strength steels (AHSS). These alloys constitute a class of high-strength, formable steels that are designed mainly as sheet products for the transportation sector. AHSS have often very complex and hierarchical microstructures consisting of ferrite, austenite, bainite, or martensite matrix or of duplex or even multiphase mixtures of these constituents, sometimes enriched with precipitates. This complexity makes it challenging to establish reliable and mechanism-based microstructure–property relationships. A number of excellent studies already exist about the different types of AHSS (such as dual-phase steels, complex phase steels, transformation-induced plasticity steels, twinning-induced plasticity steels, bainitic steels, quenching and partitioning steels, press hardening steels, etc.) and several overviews appeared in which their engineering features related to mechanical properties and forming were discussed. This article reviews recent progress in the understanding of microstructures and alloy design in this field, placing particular attention on the deformation and strain hardening mechanisms of Mn-containing steels that utilize complex dislocation substructures, nanoscale precipitation patterns, deformation-driven transformation, and twinning effects. Recent developments on microalloyed nanoprecipitation hardened and press hardening steels are also reviewed. Besides providing a critical discussion of their microstructures and properties, vital features such as their resistance to hydrogen embrittlement and damage formation are also evaluated. We also present latest progress in advanced characterization and modeling techniques applied to AHSS. Finally, emerging topics such as machine learning, through-process simulation, and additive manufacturing of AHSS are discussed. The aim of this viewpoint is to identify similarities in the deformation and damage mechanisms among these various types of advanced steels and to use these observations for their further development and maturation.

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Current Challenges and Opportunities in Microstructure-Related Properties of Advanced High-Strength Steels

Macroscopic to nanoscopic in situ investigation on yielding mechanisms in ultrafine grained medium Mn steels: Role of the austenite-ferrite interface

Manganese is normally considered as the most important alloying element in medium Mn steels. However, the influence of Mn additions on the microstructural characteristics and the ensuring mechanical properties has not been much studied. This was addressed in the present study by investigating two variants of medium Mn steels with compositions of 0.2C-7/10Mn-3Al (in wt%), subjected to intercritical annealing (IA) and tensile testing. Results showed that a higher Mn addition can effectively increase the fraction of retained austenite (RA) at ambient temperature. However, the mechanical stability of RA was reduced, due to the lower C concentration partitioned into austenite during IA treatments. The higher fraction and lower mechanical stability of RA in the 10Mn steel gave rise to an enhanced transformation-induced plasticity (TRIP) effect, which was the main contributor to its higher strain hardening rate and improved mechanical properties, confirmed by a dislocation density-based strain hardening model. The yielding behavior and the Portevin-Le Chatelier (PLC) effect of the investigated steels were also found to be altered with different austenite mechanical stability as a consequence of different Mn additions and IA temperatures. Higher deformation-induced martensite transformation (DIMT) kinetics, i.e. lower mechanical stability of austenite, resulted in a lower yield point elongation, and eventually changed the yielding to a continuous manner due to the formation of stress-induced martensite. The PLC effect only occurred in the intermediate austenite stability range, and the critical strain for the onset of jerky flow showed a first decrease and then an increasing trend with higher DIMT kinetics. The observed beneficial effect of Mn additions on mechanical property improvement in medium Mn steels offers a significant aspect for further alloy design of such steels.

Microstructural characteristics and tensile behavior of medium manganese steels with different manganese additions

An ultrahigh strength and enhanced ductility cold-rolled medium-Mn steel treated by intercritical annealing

Evolution of the substructure of a novel 12% Cr steel under creep conditions

Transformation-induced plasticity (TRIP)-assisted medium-Mn steels with a ferritic matrix containing considerable amounts of retained austenite are a promising candidate to fulfill the requirements for the third-generation of advanced high-strength steels (AHSS), which is currently under development. The influence of the intercritical annealing temperature and cooling rate on the final microstructure of a 0.1C3.5Mn and 0.1C5Mn steel, respectively, was elaborately investigated. Dilatometric experiments were carried out and additionally supported by microstructural observations. During soaking in the two-phase ferrite–austenite region and subsequent slow cooling the C and Mn concentration in the austenite increased and resulted in its chemical stabilization. The variation of the annealing temperature and cooling rate altered the amounts of ferrite, retained austenite, bainite, pearlite, and martensite in the final microstructure. Furthermore, two thermodynamical models for the prediction of the maximum retained austenite content and the optimal annealing temperature have been thoroughly evaluated in this work. It can be stated that the experimental data revealed a shift of the maximum retained austenite to higher annealing temperatures compared to the model calculations. As diffusional transformations were not considered in the applied models, slow cooling rates led to pronounced deviations between calculation and experiment, thereby showing the need for model adaptions.

Comparative Investigation of Phase Transformation Behavior as a Function of Annealing Temperature and Cooling Rate of Two Medium-Mn Steels

With the aim to increase base material creep strength and overcome the type IV cracking problem, a new design concept was developed. This so called martensitic boron–nitrogen strengthened steel (MARBN) combines boron strengthening through solid solution with precipitation strengthening by finely dispersed nitrides. In this work, uniaxial creep tests of the MARBN base material and welded joints have been carried out. The creep strength of the welded joints was analysed, and the evolution of creep damage was investigated. The creep tests of MARBN revealed increased strength of the base material of about +20% compared to the best commercially available 9Cr steel grade. At higher stress levels, the creep strength of crosswelds is between that of the MARBN base material and the conventional 9Cr base materials. Nevertheless, long term creep tests revealed a drop in creep strength of the MARBN welded joints. The underlying phenomena of crossweld creep behaviour are discussed in detail.

Creep and damage investigation of advanced martensitic chromium steel weldments for high temperature applications in thermal power plants

In recent years, a design concept for the stabilisation of the microstructure by addition of boron and nitrogen was developed. This so called martensitic boron–nitrogen strengthened steel (MARBN) combines boron strengthening by solid solution with precipitation strengthening by finely dispersed nitrides. Welded joints of MARBN steels showed no formation of a uniform fine grained region in the heat affected zone (HAZ) which is in general highly susceptible to Type IV cracking. In this work, the crossweld creep strength of a newly developed MARBN steel was analysed and the evolution of damage was investigated using synchrotron microtomography supported by electron microscopy. Three-dimensional (3D) reconstructions of the tested samples together with electron backscatter diffraction investigations revealed an intense void formation in a restricted area along small grains at prior austenite grain boundaries in the HAZ as the main reason for premature creep failures in the HAZ of welded joints.

Coline Beal

Papers

On the microstructural characteristics influencing the yielding behavior of ultra-fine grained medium-Mn steels

Evolution of the substructure of a novel 12% Cr steel under creep conditions

Comparative Investigation of Phase Transformation Behavior as a Function of Annealing Temperature and Cooling Rate of Two Medium-Mn Steels

Creep and damage investigation of advanced martensitic chromium steel weldments for high temperature applications in thermal power plants

Investigation of creep damage in advanced martensitic chromium steel weldments using synchrotron X-ray micro-tomography and EBSD