Cyclohexadienone ketals and quinols: four building blocks potentially useful for enantioselective synthesis.

Recent developments in the synthesis of C-glycosides

/pdf/theoretical-studies-of-some-transition-metal-mediated-4lpnd94u6r.pdf

Theoretical Studies of Some Transition-Metal-Mediated Reactions of Industrial and Synthetic Importance.

Recent advances in stereoselective c-glycoside synthesis

A series of Cu(I) complexes formulated as [Cu2(μ-X)2(PPh3)(L)n] were prepared with various mono- and bidentate N-heteroaromatic ligands (X = Br, I; L = 4,4‘-bipyridine, pyrazine, pyrimidine, 1,5-naphthyridine, 1,6-naphthyridine, quinazoline, N,N-dimethyl-4-aminopyridine, 3-benzoylpyridine, 4-benzoylpyridine; n = 1, 2). Single-crystal structure analyses revealed that all the complexes have planar {Cu2X2} units. Whereas those with monodentate N-heteroaromatic ligands afforded discrete dinuclear complexes, bidentate ligands formed infinite chain complexes with the ligands bridging the dimeric units. The long Cu···Cu distances (2.872−3.303 A) observed in these complexes indicated no substantial interaction between the two Cu(I) ions. The complexes showed strong emission at room temperature as well as at 80 K in the solid state. The emission spectra and lifetimes in the microsecond range were measured at room temperature and at 80 K. The emissions of the complexes varied from red to blue by the systematic sele...

Luminescence Ranging from Red to Blue: A Series of Copper(I)−Halide Complexes Having Rhombic {Cu2(μ-X)2} (X = Br and I) Units with N-Heteroaromatic Ligands

Reductive aromatization of quinol ketals: a new synthesis of C-aryl glycosides

Reductive aromatization of quinols. New convenient methods for the regiospecific synthesis of p-hydroxy C-aryl glycals

Regioselectivity in intramolecular nucleophilic aromatic substitution. Synthesis of the potent anti HIV-I 8-halo TIBO analogs

A strategy for the convergent synthesis of gilvocarcins via chromium carbene benzannulation. 1-O-Methyldefucogilvocarcin V in seven steps

Reductive and Nonreductive Aromatization of Quinol Ketal Glycals. Models for the Preparation of C-Aryl Glycoside Natural Products

Craig A. Coburn

Papers

Reductive aromatization of quinol ketals: a new synthesis of C-aryl glycosides

Reductive aromatization of quinols. New convenient methods for the regiospecific synthesis of p-hydroxy C-aryl glycals

Regioselectivity in intramolecular nucleophilic aromatic substitution. Synthesis of the potent anti HIV-I 8-halo TIBO analogs

A strategy for the convergent synthesis of gilvocarcins via chromium carbene benzannulation. 1-O-Methyldefucogilvocarcin V in seven steps

Reductive and Nonreductive Aromatization of Quinol Ketal Glycals. Models for the Preparation of C-Aryl Glycoside Natural Products