Journal ArticleDOI
Reductive aromatization of quinol ketals: a new synthesis of C-aryl glycosides
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This article is published in Journal of the American Chemical Society.The article was published on 1991-10-01. It has received 60 citations till now. The article focuses on the topics: Aryl & Aromatization.read more
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Cyclohexadienone ketals and quinols: four building blocks potentially useful for enantioselective synthesis.
Journal ArticleDOI
Luminescence Ranging from Red to Blue: A Series of Copper(I)−Halide Complexes Having Rhombic {Cu2(μ-X)2} (X = Br and I) Units with N-Heteroaromatic Ligands
TL;DR: A series of Cu(I) complexes formulated as [Cu(2)(mu-X)(2)(PPh(3))(L)(n)] were prepared with various mono- and bidentate N-heteroaromatic ligands and showed strong emission at room temperature as well as at 80 K in the solid state.
Journal ArticleDOI
Total Synthesis of Aryl C-Glycoside Natural Products: Strategies and Tactics
TL;DR: The aryl C-glycoside structure is, among the plenty of biologically active natural products, one of the distinct motifs embedded, and the synthetic strategies and tactics employed in the total synthesis of this class of natural products.
Journal ArticleDOI
Structures of the Copper(I) and Copper(II) Complexes of 2,9-Diphenyl-1,10-phenanthroline: Implications for Excited-State Structural Distortion.
TL;DR: Solution-state absorption and (1)H NMR spectra indicate that the [Cu(dpp)(2)](+) complex is fluxional in solution, rocking between two enantiomeric structures of C(2) molecular symmetry through an intermediate ofC(s)() symmetry.