D. Bromm

TL;DR: Carbene-Analgous Reactions of the Products of Dehalogenation of Dichloro-diisopropylamino)borane with Aromatic Compounds and 1,2-Dimethoxyethane as discussed by the authors.

TL;DR: The formation of the compounds C 6 H 6 · x BN(i-C 3 H 7 ) 2 ( x = 1-6) from the reaction of dichloro(diisopropylamino)borane with sodium/potassium alloy in 1,2-dimethoxyethane, has been confirmed by mass spectrometric studies (high resolution, field ionisation and collision activation using linked scan) as discussed by the authors.

TL;DR: In this paper, the reactions of subvalent species generated by the reaction of dichloro(diisopropylamino)borane with sodium/potassium alloy with unsaturated aliphatic hydrocarbons, have yielded the following compounds: the 2,5-dihydroboroles I and II from 1, 3-dienes; the 1,3-Dihydrodiboretes III and IV from alkynes; and the 1-bis(biopropyl-boryl-2-trimethylsily

TL;DR: The new 1,2,3-tris(diisopropylamino)triborolanes 1, 2, 3 and 4 have been prepared by treatment of mixtures of 2-norbornene (A), 5-methylene-2-nor-bornene, 5-ethylidene-1,5-dicarba-closo-pentaborane(5) (6) as mentioned in this paper.

TL;DR: The reaction of subvalent boron species generated by the defluorination of difluoro(diorganylamino)borane with Na/K alloy in the presence of 1,4-disubstituted benzene derivatives leads to products which contain two diisoalkylaminoboradiyl units and two remaining double bonds which are located on the substituted C atoms.