D
D. Rajagopal
Researcher at University of North Texas
Publications - 25
Citations - 230
D. Rajagopal is an academic researcher from University of North Texas. The author has contributed to research in topics: Butane & Yield (chemistry). The author has an hindex of 8, co-authored 25 publications receiving 222 citations.
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A Novel Approach to the Synthesis of 1,3,3-trinitroazetidine
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Reactions of 1-ethyl-3-azabicyclo[1.1.0]butane with electrophiles. A facile entry into new, N-substituted 3-ethylideneazetidines and 2-azetines
TL;DR: The reaction of 1-aza-3-ethylbicyclo[1.1.0] butane (3) with N 2 O 4 under a variety of experimental conditions afforded several products, 4-7, all of which resulted via addition across the strained central C(3)-N σ-bond in 3.
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Additions of X-Y Across the C(3)-N .sigma.-Bond in 1-Aza-3-ethylbicyclo[1.1.0]butane. Novel Routes to 3-Substituted Azetidines
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Addition of trimethylsilyl azide and of “mixed anhydrides” to the N-C(3) σ-bond in 3-substituted-1-azabicyclo[1.1.0]butanes†
TL;DR: Trimethylsilyl azide adds smoothly to the highly strained N-C(3) σ-bond in 3-ethyl-1-azabicyclo[1.1.0]-butane to afford an adduct, 2, that reacts in situ with a variety of electrophilic reagents (i.e., ethyl chloroformate, p-toluenesulfonyl chloride, benzoyl chloride and oxalyl chloride) to afford the corresponding N-substituted-3-azido-3
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Highly regioselective hypervalent iodine mediated ring cleavage and ring expansion reactions of some pentacyclo[5.4.0.02,6.03,10.05,9]undecane derivatives
TL;DR: In this paper, the structure of 3-hydroxy-4-oxa-5-methyl-hexacyclo[5.4.1.02,6.03,10.05,9]-undecane was established unequivocally via single crystal X-ray structural analysis.