D
Daisuke Kaneno
Researcher at Kōchi University
Publications - 33
Citations - 954
Daisuke Kaneno is an academic researcher from Kōchi University. The author has contributed to research in topics: Steric effects & Natural bond orbital. The author has an hindex of 11, co-authored 32 publications receiving 833 citations. Previous affiliations of Daisuke Kaneno include University of Tokyo & Hokkaido University.
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Stereochemical Determination of Acyclic Structures Based on Carbon−Proton Spin-Coupling Constants. A Method of Configuration Analysis for Natural Products
TL;DR: This J-based configuration analysis was applied to the stereochemical elucidation of carboxylic acid 5 derived from zooxanthellatoxin and proven to be a practical method even for natural products with complicated structures.
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Parr’s index to describe both electrophilicity and nucleophilicity
TL;DR: In this article, a new aspect of Parr's ω value was disclosed, which was originally proposed as an electrophilicity index and reformulated as a useful single scale from electrophilic to nucleophilic by introducing corresponding e values.
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Intrinsic reactivity index as a single scale directed toward both electrophilicity and nucleophilicity using frontier molecular orbitals
TL;DR: A theoretical intrinsic reactivity index (IRI) was introduced by as mentioned in this paper through analysis of the ω, ǫ correlation (Tetrahedron Lett.2013, 54, 339,342).
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Theoretical study on the mechanism and diastereoselectivity of NaBH4 reduction.
TL;DR: A new transition state structure model that contains complexation of the carbonyl oxygen with sodium cation is proposed and predicted diastereoselectivity of the reduction of some substituted cyclohexanones applying this novel transition state model is in good agreement with experimental data, showing its validity and effectiveness to investigate the diasterenity of NaBH4 reduction of other ketones.
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The Origin of Cis Effect in 1,2-Dihaloethenes : The Quantitative Comparison of Electron Delocalizations and Steric Exchange Repulsions
TL;DR: The "cis effect" as discussed by the authors is a phenomenon in which the cis isomer is more stable than the corresponding trans isomer or almost the same stability in some molecules with double bonds.