D
Daniel B. Leznoff
Researcher at Simon Fraser University
Publications - 173
Citations - 4302
Daniel B. Leznoff is an academic researcher from Simon Fraser University. The author has contributed to research in topics: Coordination polymer & Ligand. The author has an hindex of 33, co-authored 163 publications receiving 3900 citations. Previous affiliations of Daniel B. Leznoff include Trinity Western University & University of Maine.
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The use of aurophilic and other metal–metal interactions as crystal engineering design elements to increase structural dimensionality
TL;DR: This tutorial review will explore the methods by which gold(I) and other d10 and d8 metal centres have been employed to increase structural dimensionality via the formation of metal-metal interactions.
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Cu[Au(CN)2]2(DMSO)2: golden polymorphs that exhibit vapochromic behavior.
TL;DR: The network-stabilizing gold-gold interactions and the flexible coordination sphere of Cu(II) probably facilitate reversible solvent exchange at room temperature, and the vapochromic behavior of the two polymorphs is essentially identical.
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Polymorphism of Zn[Au(CN)2]2 and Its Luminescent Sensory Response to NH3 Vapor
TL;DR: Upon exposure to ammonia vapor, the polymers altered their structures and emission energies, with the emission wavelength shifting to 500 nm for {Zn(NH3)2[Au(CN)2]2}, which adopts a two-dimensional layer structure with octahedral, trans-oriented NH3 groups.
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Gold−Gold Interactions as Crystal Engineering Design Elements in Heterobimetallic Coordination Polymers
TL;DR: A series of coordination polymers containing Cu(II) and [Au(CN)(2)](-) units has been prepared, thus illustrating that such "aurophilic" interactions can be powerful tools for increasing structural dimensionality in supramolecular systems.
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Heterobimetallic Coordination Polymers Incorporating [M(CN)2]- (M = Cu, Ag) and [Ag2(CN)3]- Units: Increasing Structural Dimensionality via M−M‘ and M···NC Interactions
Carolyn J. Shorrock,Bao-Yu Xue,Peter B. Kim,Raymond J. Batchelor,Brian O. Patrick,Daniel B. Leznoff +5 more
TL;DR: A series of new heterometallic coordination polymers has been prepared from the reaction of metal-ligand cations and KAg(CN)(2) units, showing that Ag(I) is a more efficient mediator of magnetic exchange as compared to Au(I).