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Daria V. Ignat'eva

Researcher at Moscow State University

Publications -  25
Citations -  491

Daria V. Ignat'eva is an academic researcher from Moscow State University. The author has contributed to research in topics: Trifluoromethylation & Trifluoromethyl. The author has an hindex of 14, co-authored 25 publications receiving 473 citations. Previous affiliations of Daria V. Ignat'eva include Humboldt State University.

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Journal ArticleDOI

Synthesis, Characterization, and Theoretical Study of Stable Isomers of C70(CF3)n (n = 2, 4, 6, 8, 10)

TL;DR: The results demonstrate that thermally stable C70( CF3)n isomers tend to have their CF3 groups arranged on isolated para-C6(CF3)2 hexagons and/or on a ribbon of edge-sharing meta- and-or para-Para-para ribbon includes three polar hexagons.
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Synthesis, structure, and theoretical study of lower trifluoromethyl derivatives of [60]fullerene

TL;DR: A number of C60(CF3)n compounds with n = 2-10 have been synthesized by the reaction of C 60 with silver trifluoroacetate and successfully isolated by means of HPLC as discussed by the authors.
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Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18.

TL;DR: C70( CF3)16 and C70(CF3)18, the first trifluoromethylated fullerene derivatives to comprise a pair of adjacent CF3 groups, have been isolated from a mixture obtained via reaction of C70 with CF3I.
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Preparation, crystallographic characterization and theoretical study of two isomers of C70(CF3)12

TL;DR: Two isomers of C 70(CF3)12 have been isolated from a mixture obtained by trifluoromethylation of C70 with CF3I; their molecular structures determined by X-ray crystallography are in good agreement with the results of theoretical DFT calculations for the most stable C70( CF3) 12 isomers.
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Higher trifluoromethylated derivatives of C60, C60(CF3)16 and C60(CF3)18. Synthesis, structure, and theoretical study

TL;DR: In this article, the molecular structures of the four new compounds have been determined by means of X-ray single crystal diffraction and discussed in terms of mechanistic pathways of their formation and relative stability according to the DFT calculations.