介绍了Kirk—Othmer Encyclopedia of Chemical Technology（化工技术百科全书）（第五版）电子图书网络版数据库，并对该数据库使用方法和检索途径作出了说明，且结合实例简单地介绍了该数据库的检索方法。

Kirk-Othmer Encyclopedia of Chemical Technology数据库介绍及实例

Boron carbide, which has a high melting point, outstanding hardness, good mechanical properties, low specific weight, great resistance to chemical agents and high neutron absorption cross-section (10BxC, x>4) is currently used in high-technology industries—fast-breeders, lightweight armors and high-temperature thermoelectric conversion.

The contents of this review are: (1) introduction; (2) preparations—industrial preparative routes, powders, sintering (additives, pressureless, hot pressing, HIP); laboratory methods of synthesis (CVD, PVD, plasma, crystal growth); (3) analytical characterization; (4) phase diagram—a peritectic, nearly pure boron, and a wide phase homogeneity range (B4C-B10·5C); (5) rhombohedral crystal structure—a comprehensive model of the whole solid solution is proposed; (6) chemical properties; (7) physical properties—density, mechanical (strength, hardness, toughness) and thermo-electrical properties; (8) main industrial applications; (9) conclusion.

Boron carbide ― a comprehensive review

Bull. Chem. Soc. Jpn. への投稿のすすめ

Aryl sulfonyl chlorides (e.g. Ts-Cl) are beloved of organic chemists as the most commonly used S(VI) electrophiles, and the parent sulfuryl chloride, O2 S(VI) Cl2 , has also been relied on to create sulfates and sulfamides. However, the desired halide substitution event is often defeated by destruction of the sulfur electrophile because the S(VI) Cl bond is exceedingly sensitive to reductive collapse yielding S(IV) species and Cl(-) . Fortunately, the use of sulfur(VI) fluorides (e.g., R-SO2 -F and SO2 F2 ) leaves only the substitution pathway open. As with most of click chemistry, many essential features of sulfur(VI) fluoride reactivity were discovered long ago in Germany.6a Surprisingly, this extraordinary work faded from view rather abruptly in the mid-20th century. Here we seek to revive it, along with John Hyatt's unnoticed 1979 full paper exposition on CH2 CH-SO2 -F, the most perfect Michael acceptor ever found.98 To this history we add several new observations, including that the otherwise very stable gas SO2 F2 has excellent reactivity under the right circumstances. We also show that proton or silicon centers can activate the exchange of SF bonds for SO bonds to make functional products, and that the sulfate connector is surprisingly stable toward hydrolysis. Applications of this controllable ligation chemistry to small molecules, polymers, and biomolecules are discussed.

Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry

Electrophilic Perfluoroalkylating Agents.

Selectivity in the solvolysis in binary solvents of 1-adamantyl derivatives bearing leaving groups that depart as neutral molecules

Kinetics and mechanism of the reactions of allyl halides with silver nitrate in acetonitrile

The specific rates of solvolysis of propargyl chloroformate (1) are analyzed in 22 solvents of widely varying nucleophilicity and ionizing power values at 25.0 °C using the extended Grunwald-Winstein equation. Sensitivities to solvent nucleophilicity (l) of 1.37 and to solvent ionizing power (m) of 0.47 suggest a bimolecular process with the formation of a tetrahedral intermediate. A plot of the rates of solvolysis of 1 against those previously reported for phenyl chloroformate (2) results in a correlation coefficient (R) of 0.996, a slope of 0.86, and an F-test value of 2161. The unequivocal correlation between these two substrates attest that the stepwise association-dissociation (A(N) + D(N)) mechanism previously proposed for 2 is also operative in 1.

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A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate

Reactions of 2-Bromo-2-(α-halogenobenzyl)-1-indanones

A series of experiments that exposes students to the synthesis of ferrocenylmethyl acetate, different methods for monitoring a reaction, and the analysis of kinetic data.

Dennis N. Kevill

Papers

Selectivity in the solvolysis in binary solvents of 1-adamantyl derivatives bearing leaving groups that depart as neutral molecules

Kinetics and mechanism of the reactions of allyl halides with silver nitrate in acetonitrile

A Study of Solvent Effects in the Solvolysis of Propargyl Chloroformate

Reactions of 2-Bromo-2-(α-halogenobenzyl)-1-indanones

Synthesis and solvolysis of ferrocenylmethyl acetate: A multistep synthesis and kinetics experiment