E
E. V. Bakhmutova
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 11
Citations - 333
E. V. Bakhmutova is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Nuclear magnetic resonance spectroscopy & Hydride. The author has an hindex of 9, co-authored 11 publications receiving 328 citations.
Papers
More filters
Journal ArticleDOI
Unusual hydrogen bonds with a hydride atom in boron hydrides acting as proton acceptor. spectroscopic and theoretical studies
Lina M. Epstein,Elena S. Shubina,E. V. Bakhmutova,Liliya N. Saitkulova,Vladimir I. Bakhmutov,Anatolii L. Chistyakov,Ivan V. Stankevich +6 more
TL;DR: In this paper, the interaction of different proton donors with ionic (Bu4NBH4) and neutral (BH3NEt3, BH3P(OEt)3) boron hydrides was studied by IR and NMR spectroscopy in solution (CH2Cl2, C6H14, and C6D12).
Journal ArticleDOI
In-depth NMR and IR study of the proton transfer equilibrium between [{(MeC(CH2PPh2)3}Ru(CO)H2] and hexafluoroisopropanol
Vladimir I. Bakhmutov,E. V. Bakhmutova,Natalia V. Belkova,Claudio Bianchini,L.M. Epstein,Dante Masi,Maurizio Peruzzini,Elena S. Shubina,Evgenii V. Vorontsov,Fabrizio Zanobini +9 more
TL;DR: In this article, the (carbonyl)dihydride complex (triphos)Ru(CO)H2] (2) has been synthesized by reaction of the ruthenate [(triphson)RuH3]K (Triphos = MeC(CH2PPh2)3) with ethanol saturated with CO.
Journal ArticleDOI
Crown Compounds for Anions: Sandwich and Half-Sandwich Complexes of Cyclic Trimeric Perfluoro-o-phenylenemercury with Polyhedral closo-[B10H10]2− and closo-[B12H12]2− Anions
Elena S. Shubina,I. A. Tikhonova,E. V. Bakhmutova,Fedor M. Dolgushin,Mikhail Yu. Antipin,Vladimir I. Bakhmutov,Igor B. Sivaev,Lylia N. Teplitskaya,Igor T. Chizhevsky,I. V. Pisareva,Vladimir I. Bregadze,Lina M. Epstein,Vladimir B. Shur +12 more
TL;DR: X-ray diffraction studies of 3 and 5 have revealed that these compounds have unusual sandwich structures, in which the polyhedral di-anion is located between the planes of two molecules of 1 and is bonded to each of them through two types of B-H-Hg bridges.
Journal ArticleDOI
In situ IR and NMR study of the interactions between proton donors and the Re(I) hydride complex [{MeC(CH2PPh2)3}Re (CO)2H]. ReH…H bonding and proton-transfer pathways
Elena S. Shubina,Natalia V. Belkova,E. V. Bakhmutova,Evgenii V. Vorontsov,Vladimir I. Bakhmutov,A. V. Ionidis,Claudio Bianchini,Lorenza Marvelli,Maurizio Peruzzini,Lina M. Epstein +9 more
TL;DR: In this paper, it has been shown that the [(triphos)Re(CO)2H…HOR] adducts are thermodynamically more stable than any H-bond adduct.
Journal ArticleDOI
Dihydrogen bonding of decahydro-closo-decaborate(2−) and dodecahydro-closo-dodecaborate(2−) anions with proton donors: experimental and theoretical investigation
Elena S. Shubina,E. V. Bakhmutova,Andrey M. Filin,Igor B. Sivaev,Lylia N. Teplitskaya,Anatolii L. Chistyakov,Ivan V. Stankevich,Vladimir I. Bakhmutov,Vladimir I. Bregadze,Lina M. Epstein +9 more
TL;DR: In this paper, the BH⋯HO hydrogen bonding between the boron hydrides and the OH proton donors in solution was investigated in low polarity media and the site of coordination for [B 10 H 10 ] 2− and [B 12 H 12 ] 2 − was found to be hydride hydrogen.