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Natalia V. Belkova
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 145
Citations - 3448
Natalia V. Belkova is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Hydride & Hydrogen bond. The author has an hindex of 27, co-authored 129 publications receiving 3150 citations. Previous affiliations of Natalia V. Belkova include Russian Academy of Sciences & Irkutsk State University.
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Comparative 16S rRNA Analysis of Lake Bacterioplankton Reveals Globally Distributed Phylogenetic Clusters Including an Abundant Group of Actinobacteria
Frank Oliver Glöckner,Evgeny Zaichikov,Natalia V. Belkova,Ludmilla Denissova,Jakob Pernthaler,Annelie Pernthaler,Rudolf Amann +6 more
TL;DR: A combination of phylogenetic analysis and FISH was used to reveal 16 globally distributed sequence clusters and to confirm the broad distribution, abundance, and high biomass of members of the class Actinobacteria in freshwater ecosystems.
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Diverse World of Unconventional Hydrogen Bonds
TL;DR: The view of unconventional intermolecular hydrogen bonds (HBs) for organometallic complexes and transition-metal or main-group hydrides is presented and there is still much to explore in terms of the prediction of HB properties and control of protonation/deprotonation processes.
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Spectroscopic Evidence for Intermolecular M−H···H−OR Hydrogen Bonding: Interaction of WH(CO)2(NO)L2 Hydrides with Acidic Alcohols
Elena S. Shubina,Natalia V. Belkova,Aleksandr N. Krylov,Evgeni V. Vorontsov,L.M. Epstein,Dmitri Gusev,Martina Niedermann,Heinz Berke +7 more
TL;DR: Intermolecular hydrogen bonding of acidic alcohols to the hydride ligand of WH(CO)2(NO)L2 (L = PMe3), PEt3 (2), P(OiPr)3 (3), PPh3 (4)) has been observed and characterized by IR and NMR spectroscopy in hexane, toluene-d8, and CD2Cl2 solutions as mentioned in this paper.
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Hydrogen and Dihydrogen Bonds in the Reactions of Metal Hydrides
TL;DR: Up-to-date experimental and computational studies of the structural, energetic, and spectroscopic parameters and natures of dihydrogen-bonded complexes of the form M-H···H-X are collated, as such species are now known for a wide variety of hydrido compounds.
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Influence of media and homoconjugate pairing on transition metal hydride protonation. An IR and DFT study on proton transfer to CpRuH(CO)(PCy3).
Natalia V. Belkova,Maria Besora,Lina M. Epstein,Agustí Lledós,Feliu Maseras,Elena S. Shubina +5 more
TL;DR: The role of homoconjugate pairs [ROHOR](-) in the protonation is analyzed by means of the inclusion of an additional ROH molecule in the calculations, and solvent effects in the calculation with the PCM method are presented.