Emma I. Rogers

TL;DR: The recent literature is surveyed to explore the nature of voltammetry in room temperature ionic liquids and the extent of similarities with conventional electrochemical solvents is reported and some surprising differences are noted.

TL;DR: In this paper, the electrochemical behavior of Ferrocene, Fc, and cobaltocenium hexafluorophosphate, CcPF6, has been reported for use as internal reference redox couples in room-temperature ionic liquids.

TL;DR: In the six ionic liquids, the Stokes-Einstein relationship was found to apply only very approximately for oxygen, considered in relationship to the behavior of other diverse solutes in RTILs.

TL;DR: In this article, the diffusion coefficients of both ferrocene and ferrocenium (Fc +) in acetonitrile containing 0.1 M tetra-n-butylammoniumperchlorate (TBAPF6) or 0. 1 M tetrasn-methanehexafluorophosphate (TBPF6), were determined using the technique of double potential step chronoamperometry at a microdisk electrode.

TL;DR: In this paper, the cathodic and anodic potential limits of eleven different ionic liquids were determined at a mercury hemisphere electrode, and it was shown that Ionic liquids containing the phosphonium cation (tri(n-hexyl)tetradecylphosphonium, [P14,6,6 6, 6,6]+) give the largest potential window, especially when coupled with a trifluorotris(pentafluoroethyl)phosphate, [FAP]−, or bis(triffluorometh