E
Eric Saint-Aman
Researcher at University of Grenoble
Publications - 140
Citations - 4674
Eric Saint-Aman is an academic researcher from University of Grenoble. The author has contributed to research in topics: Ferrocene & Ligand. The author has an hindex of 38, co-authored 137 publications receiving 4326 citations. Previous affiliations of Eric Saint-Aman include Centre national de la recherche scientifique & Joseph Fourier University.
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pH-controlled change of the metal coordination in a dicopper(II) complex of the ligand H-BPMP: crystal structures, magnetic properties, and catecholase activity.
Stéphane Torelli,Catherine Belle,Isabelle Gautier-Luneau,Jean-Louis Pierre,Eric Saint-Aman,Jean-Marc Latour,L. Le Pape,Dominique Luneau +7 more
TL;DR: The results indicate that the pH dependence of the catalytic abilities of the complexes is related to changes in the coordination sphere of the metal centers.
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Imidazolate-bridged dicopper(II) and copper-zinc complexes of a macrobicyclic ligand (cryptand). A possible model for the chemistry of Cu-Zn superoxide dismutase
Jean-Louis Pierre,Pierre Chautemps,Sidi M. Refaif,Claude Béguin,Abdelilah El Marzouki,Guy Serratrice,Eric Saint-Aman,Paul Rey +7 more
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Dicopper(II) Complexes of H-BPMP-Type Ligands: pH-Induced Changes of Redox, Spectroscopic (19F NMR Studies of Fluorinated Complexes), Structural Properties, and Catecholase Activities
Catherine Belle,Claude Béguin,Isabelle Gautier-Luneau,Sylvain Hamman,Christian Philouze,Jean-Louis Pierre,Fabrice Thomas,Stéphane Torelli,Eric Saint-Aman,Michel Bonin +9 more
TL;DR: The studies show the pH-dependence for the catalytic abilities of the complexes, related with changes in the coordination sphere of the metal centers, and investigations of the catechol oxidase activities are of interest in modeling thecatecholase enzyme active site and in understanding aspects of structure/reactivity.
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Valence Tautomerism in Octahedral and Square‐Planar Phenoxyl–Nickel(II) Complexes: Are Imino Nitrogen Atoms Good Friends?
Olaf Rotthaus,Fabrice Thomas,Olivier Jarjayes,Christian Philouze,Eric Saint-Aman,Jean-Louis Pierre +5 more
TL;DR: An intramolecular electron transfer (valence tautomerism) is promoted by the geometrical changes, from square planar to octahedral, around the metal center.
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Ferrocene-appended porphyrins: Syntheses and properties
TL;DR: In this article, a review article focuses on the syntheses and potential applications of ferrocene-appended porphyrin architectures, including the connection at a meso position through a direct linkage, a conjugated or saturated spacer or using a non-covalent approach.