F
François Nief
Researcher at École Polytechnique
Publications - 79
Citations - 2081
François Nief is an academic researcher from École Polytechnique. The author has contributed to research in topics: Ligand & Samarium. The author has an hindex of 26, co-authored 79 publications receiving 1925 citations. Previous affiliations of François Nief include Centre national de la recherche scientifique.
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Journal ArticleDOI
New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity.
Thibault Cantat,Florian Jaroschik,François Nief,Louis Ricard,Nicolas Mézailles,Pascal Le Floch +5 more
TL;DR: New samarium carbene complexes have been synthesized and characterized by X-ray diffraction analysis; the carbenic nature was assessed by reactivity studies.
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Dinitrogen reduction and C-H activation by the divalent organoneodymium complex [(C5H2tBu3)2Nd(mu-I)K([18]crown-6)].
Florian Jaroschik,Aurélien Momin,François Nief,Xavier F. Le Goff,Glen B. Deacon,Peter C. Junk +5 more
TL;DR: The first divalent organoneodymium complex has been isolated and characterized by X-ray crystallography and undergoes C[BOND]H activation of a ligand tert-butyl group to form a crystallizable "tuck-in" complex (see scheme).
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Isolation of Stable Organodysprosium(II) Complexes by Chemical Reduction of Dysprosium(III) Precursors
TL;DR: In this paper, the reduction of bis(tri-tert-butylcyclopentadienyl)dysprosium(III) complexes by potassium/graphite in the presence of a crown ether has been shown to yield structurally characterized divalent organolanthanide compounds.
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Non-classical divalent lanthanide complexes
TL;DR: These non-classical divalent compounds show exceptional reactivity as some of them have been shown to activate dinitrogen at room temperature, together with related reduced divalent-like systems, and to undergo spontaneous intramolecular carbon-hydrogen bond activation.
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Complexes containing bonds between group 3, lanthanide or actinide metals and non-first-row main group elements (excluding halogens)
TL;DR: A comprehensive review of coordination complexes exhibiting bonds between a group 3, lanthanide or actinide metal and a group 14, group 15 or group 16 heteroelement, excluding those of the first row of the periodic table, is presented in this article.