The resonant modes of plasmonic nanoparticle structures made of gold or silver endow them with an ability to manipulate light at the nanoscale. However, owing to the high light losses caused by metals at optical wavelengths, only a small fraction of plasmonics applications have been realized. Kuznetsov et al. review how high-index dielectric nanoparticles can offer a substitute for these metals, providing a highly flexible and low-loss route to the manipulation of light at the nanoscale.

Science , this issue p. [10.1126/science.aag2472][1]

 [1]: /lookup/doi/10.1126/science.aag2472

http://science.sciencemag.org/content/sci/354/6314/aag2472.full.pdf

Optically resonant dielectric nanostructures

Metamaterials, artificial electromagnetic media that are structured on the subwavelength scale, were initially suggested for the negative-index 'superlens'. Later metamaterials became a paradigm for engineering electromagnetic space and controlling propagation of waves: the field of transformation optics was born. The research agenda is now shifting towards achieving tunable, switchable, nonlinear and sensing functionalities. It is therefore timely to discuss the emerging field of metadevices where we define the devices as having unique and useful functionalities that are realized by structuring of functional matter on the subwavelength scale. In this Review we summarize research on photonic, terahertz and microwave electromagnetic metamaterials and metadevices with functionalities attained through the exploitation of phase-change media, semiconductors, graphene, carbon nanotubes and liquid crystals. The Review also encompasses microelectromechanical metadevices, metadevices engaging the nonlinear and quantum response of superconductors, electrostatic and optomechanical forces and nonlinear metadevices incorporating lumped nonlinear components.

/pdf/from-metamaterials-to-metadevices-4vgaose515.pdf

From metamaterials to metadevices.

The ideal material for nanophotonic applications will have a large refractive index at optical frequencies, respond to both the electric and magnetic fields of light, support large optical chirality and anisotropy, confine and guide light at the nanoscale, and be able to modify the phase and amplitude of incoming radiation in a fraction of a wavelength. Artificial electromagnetic media, or metamaterials, based on metallic or polar dielectric nanostructures can provide many of these properties by coupling light to free electrons (plasmons) or phonons (phonon polaritons), respectively, but at the inevitable cost of significant energy dissipation and reduced device efficiency. Recently, however, there has been a shift in the approach to nanophotonics. Low-loss electromagnetic responses covering all four quadrants of possible permittivities and permeabilities have been achieved using completely transparent and high-refractive-index dielectric building blocks. Moreover, an emerging class of all-dielectric metamaterials consisting of anisotropic crystals has been shown to support large refractive index contrast between orthogonal polarizations of light. These advances have revived the exciting prospect of integrating exotic electromagnetic effects in practical photonic devices, to achieve, for example, ultrathin and efficient optical elements, and realize the long-standing goal of subdiffraction confinement and guiding of light without metals. In this Review, we present a broad outline of the whole range of electromagnetic effects observed using all-dielectric metamaterials: high-refractive-index nanoresonators, metasurfaces, zero-index metamaterials and anisotropic metamaterials. Finally, we discuss current challenges and future goals for the field at the intersection with quantum, thermal and silicon photonics, as well as biomimetic metasurfaces.

All-dielectric metamaterials

Photonic metamaterials are man-made structures composed of tailored micro- or nanostructured metallodielectric subwavelength building blocks. This deceptively simple yet powerful concept allows the realization of many new and unusual optical properties, such as magnetism at optical frequencies, negative refractive index, large positive refractive index, zero reflection through impedance matching, perfect absorption, giant circular dichroism and enhanced nonlinear optical properties. Possible applications of metamaterials include ultrahigh-resolution imaging systems, compact polarization optics and cloaking devices. This Review describes recent progress in the fabrication of three-dimensional metamaterial structures and discusses some of the remaining challenges.

Past achievements and future challenges in the development of three-dimensional photonic metamaterials

Metamaterials are composed of periodic subwavelength metal/dielectric structures that resonantly couple to the electric and/or magnetic components of the incident electromagnetic fields, exhibiting properties that are not found in nature. This class of micro- and nano-structured artificial media have attracted great interest during the past 15 years and yielded ground-breaking electromagnetic and photonic phenomena. However, the high losses and strong dispersion associated with the resonant responses and the use of metallic structures, as well as the difficulty in fabricating the micro- and nanoscale 3D structures, have hindered practical applications of metamaterials. Planar metamaterials with subwavelength thickness, or metasurfaces, consisting of single-layer or few-layer stacks of planar structures, can be readily fabricated using lithography and nanoprinting methods, and the ultrathin thickness in the wave propagation direction can greatly suppress the undesirable losses. Metasurfaces enable a spatially varying optical response (e.g. scattering amplitude, phase, and polarization), mold optical wavefronts into shapes that can be designed at will, and facilitate the integration of functional materials to accomplish active control and greatly enhanced nonlinear response. This paper reviews recent progress in the physics of metasurfaces operating at wavelengths ranging from microwave to visible. We provide an overview of key metasurface concepts such as anomalous reflection and refraction, and introduce metasurfaces based on the Pancharatnam-Berry phase and Huygens' metasurfaces, as well as their use in wavefront shaping and beam forming applications, followed by a discussion of polarization conversion in few-layer metasurfaces and their related properties. An overview of dielectric metasurfaces reveals their ability to realize unique functionalities coupled with Mie resonances and their low ohmic losses. We also describe metasurfaces for wave guidance and radiation control, as well as active and nonlinear metasurfaces. Finally, we conclude by providing our opinions of opportunities and challenges in this rapidly developing research field.

A review of metasurfaces: physics and applications.

Mie resonance-based dielectric metamaterials

We report on the tunability, by a magnetic field, of a negative permeability metamaterial consisting of stacked arrays of broadside-coupled split ring resonators infiltrated with liquid crystals (LCs). The resonant frequency shift was numerically assessed by a rigorous anisotropic analysis of the reorientation of LC molecules. Experiments were carried out with a prototype designed and fabricated for X-band operation and infiltrated with a nematic compound with optical birefringence Δn=0.18. Scattering parameters vectorial analysis shows a good agreement between the resonant frequency shifts predicted under anisotropic conditions and those measured under static magnetic control.

Magnetic control of negative permeability metamaterials based on liquid crystals

We report on a negative-zero-positive metamaterial based on an omega-type microstructure with special attention on the nonvanishing group velocity for a zero refractive index. We first investigate the dispersion characteristics by full wave analysis, by stressing the necessary conditions of equality between the electric and magnetic plasma frequencies which are characteristic of the dispersion of the effective permittivity and permeability. Also, tuning of the gapless transition frequency between the left and right-handed dispersion branches was analyzed when the permittivity of the host substrate is changed. Last, we demonstrate experimentally the balanced composite character of the dispersion by frequency and angle-resolved transmission measurements, carried out at centimeter wavelengths on slabs and wedge-type prototypes, respectively.

Negative-zero-positive metamaterial with omega-type metal inclusions

Negative-zero-positive index refraction was demonstrated numerically on the basis of full-wave analysis of a microstructured omega-type array and experimentally via angle resolved transmission measurement of a prism-type prototype. The experimental results are interpreted in terms of characteristic impedance and refractive index retrieved by a Fresnel inversion technique. The possibility to balance the dispersion characteristics with a negative-zero-positive index is demonstrated over X - and Ku -bands.

Negative-Zero-Positive Refractive Index in a Prism-Like Omega-Type Metamaterial

We demonstrate numerically and experimentally a magnetically tunable negative permeability metamaterial consisting of an array of broadside coupled split ring resonators infiltrated with liquid crystals (LCs). We stress by a comparative analysis of the LC influence on the resonant frequency under isotropic and anisotropic conditions, the specificities of the tunability of the electromagnetic properties via the substrate permittivity tensor. Experiments were carried out on the basis of a prototype designed and fabricated for X-band operation and infiltrated with a nematic LC with birefringence Deltan=0.18. Scattering parameters analysis shows a resonant frequency shift of 0.3 GHz obtained by reorienting the layered LC by means of permanent magnets; these results being in good agreement with the anisotropic theoretical approach.

Fuli Zhang

Papers

Mie resonance-based dielectric metamaterials

Magnetic control of negative permeability metamaterials based on liquid crystals

Negative-zero-positive metamaterial with omega-type metal inclusions

Negative-Zero-Positive Refractive Index in a Prism-Like Omega-Type Metamaterial

Magnetic Control of Negative Permeability Metamaterials based on Liquid Crystals