Analysis and abatement of air pollution involve a variety of technical disciplines. Formation of the most prevalent pollutants occurs during the combustion process, a tightly coupled system involving fluid flow, mass and energy transport, and chemical kinetics. Its complexity is exemplified by the fact that, in many respects, the simplest hydrocarbon combustion, the methane-oxygen flame, has been quantitatively modeled only within the last several years. Nonetheless, the development of combustion modifications aimed at minimizing the formation of the unwanted by-products of burning fuels requires an understanding of the combustion process. Fuel may be available in solid, liquid, or gaseous form; it may be mixed with the air ahead of time or only within the combustion chamber; the chamber itself may vary from the piston and cylinder arrangement in an automobile engine to a 10-story-high boiler in the largest power plant; the unwanted byproducts may remain as gases, or they may, upon cooling, form small particles. 

The only effective way to control air pollution is to prevent the release of pollutants at the source. Where pollutants are generated in combustion, modifications to the combustion process itself, for example in the manner in which the fuel and air are mixed, can be quite effective in reducing their formation. Most situations, whether a combustion or an industrial process, however, require some degree of treatment of the exhaust gases before they are released to the atmosphere. Such treatment can involve intimately contacting the effluent gases with liquids or solids capable of selectively removing gaseous pollutants or, in the case of particulate pollutants, directing the effluent flow through a device in which the particles are captured on surfaces. 

The study of the generation and control of air pollutants can be termed air pollution engineering and is the subject of this book. Our goal here is to present a rigorous and fundamental analysis of the production of air pollutants and their control. The book is intended for use at the senior or first-year graduate level in chemical, civil, environmental, and mechanical engineering curricula. We assume that the student has had basic first courses in thermodynamics, fluid mechanics, and heat transfer. The material treated in the book can serve as the subject of either a full-year or a one-term course, depending on the choice of topics covered. 

In the first chapter we introduce the concept of air pollution engineering and summarize those species classified as air pollutants. Chapter 1 also contains four appendices that present certain basic material that will be called upon later in the book. This material includes chemical kinetics, the basic equations of heat and mass transfer, and some elementary ideas from probability and turbulence. 

Chapter 2 is a basic treatment of combustion, including its chemistry and the role of mixing processes and flame structure. Building on the foundation laid in Chapter 2, we present in Chapter 3 a comprehensive analysis of the formation of gaseous pollutants in combustion. Continuing in this vein, Chapter 4 contains a thorough treatment of the internal combustion engine, including its principles of operation and the mechanisms of formation of pollutants therein. Control methods based on combustion modification are discussed in both Chapters 3 and 4. 

Particulate matter (aerosols) constitutes the second major category of air pollutants when classified on the basis of physical state. Chapter 5 is devoted to an introduction to aerosols and principles of aerosol behavior, including the mechanics of particles in flowing fluids, the migration of particles in external force fields, Brownian motion of small particles, size distributions, coagulation, and formation of new particles from the vapor by homogeneous nucleation. Chapter 6 then treats the formation of particles in combustion processes. 

Chapters 7 and 8 present the basic theories of the removal of particulate and gaseous pollutants, respectively, from effluent streams. We cover all the major air pollution control operations, such as gravitational and centrifugal deposition, electrostatic precipitation, filtration, wet scrubbing, gas absorption and adsorption, and chemical reaction methods. Our goal in these two chapters, above all, is to carefully derive the basic equations governing the design of the control methods. Limited attention is given to actual equipment specification, although with the material in Chapters 7 and 8 serving as a basis, one will be able to proceed to design handbooks for such specifications. 

Chapters 2 through 8 treat air pollution engineering from a process-by-process point of view. Chapter 9 views the air pollution control problem for an entire region or airshed. To comply with national ambient air quality standards that prescribe, on the basis of health effects, the maximum atmospheric concentration level to be attained in a region, it is necessary for the relevant governmental authority to specify the degree to which the emissions from each of the sources in the region must be controlled. Thus it is generally necessary to choose among many alternatives that may lead to the same total quantity of emission over the region. Chapter 9 establishes a framework by which an optimal air pollution control plan for an airshed may be determined. In short, we seek the least-cost combination of abatement measures that meets the necessary constraint that the total emissions not exceed those required to meet an ambient air quality standard. 

Once pollutants are released into the atmosphere, they are acted on by a variety of chemical and physical phenomena. The atmospheric chemistry and physics of air pollution is indeed a rich arena, encompassing the disciplines of chemistry, meteorology, fluid mechanics, and aerosol science. As noted above, the subject matter of the present book ends at the stack (or the tailpipe); those readers desiring a treatment of the atmospheric behavior of air pollutants are referred to J. H. Seinfeld, Atmospheric Chemistry and Physics of Air Pollution (Wiley-Interscience, New York, 1986). 

We wish to gratefully acknowledge David Huang, Carol Jones, Sonya Kreidenweis, Ranajit Sahu, and Ken Wolfenbarger for their assistance with calculations in the book.
Finally, to Christina Conti, our secretary and copy editor, who, more than anyone else, kept safe the beauty and precision of language as an effective means of communication, we owe an enormous debt of gratitude. She nurtured this book as her own; through those times when the task seemed unending, she was always there to make the road a little smoother. 

R. C. Flagan
J. H. Seinfeld

Fundamentals of Air Pollution Engineering

Studies of aromatic hydrocarbon formation mechanisms in flames: Progress towards closing the fuel gap

Emission characteristics of a spark-ignition engine fuelled with gasoline-n-butanol blends in combination with EGR

Homogeneous Charge Compression Ignition (HCCI) combustion: Implementation and effects on pollutants in direct injection diesel engines

Correlations for the ignition delay and combustion energy release intervals in a homogeneous charge, spark-ignited engine are developed. After incorporation within a simplified engine cycle simulation, predicted values of these two combustion parameters are compared to experimental engine data. The correlations are based on four fundamental quantities--the turbulent integral scale, the turbulent micro-scale, the turbulent intensity, and the laminar flame speed. The major assumptions include: (1) the turbulent integral scale is proportional to the instantaneous chamber height prior to flame initiation; (2) angular momentum is conserved in the individual turbulent eddies ahead of the flame front (i.e., a ''rapid distortion'' turbulence model); and (3) the turbulent intensity scales with the mean piston speed. Two empirical constants scale the correlations to a given engine. Predicted values for the ignition delay and burn intervals show good agreement with experimental results for wide variations in engine operating and design conditions (e.g., engine speed and load, spark timing, EGR, air-fuel ratio, and compression ratio). In addition, the shapes of the predicted mass fraction burned curves agree well with published data.

The Prediction of Ignition Delay and Combustion Intervals for a Homogeneous Charge, Spark Ignition Engine

A super-extended zel'dovich mechanism for nox modeling and engine calibration

Modeling of HCCI Combustion and Emissions Using Detailed Chemistry

A model of the four-stroke S.I. engine cycle has been developed which predicts fuel consumption, NOx and HC emissions as a function of engine design and operating conditions. The model is primarily thermodynamic in nature containing no formal spatial dependence. The major new features of the model are: first, a treatment of heat transfer which confines heat losses to a boundary layer region surrounding a central adiabatic core; second, an integral boundary-layer analysis of in-cylinder burnup of quenched hydrocarbons; and third, a calculation of exhaust port HC oxidation which considers the temperature history of each element of gas leaving the cylinder. The main adjustable parameters of the model relate to the rate of heat transfer and the ratio of the two-plate quench to the single-wall thickness. An extensive comparison of model predictions with experimental CFR engine data is presented. The results show excellent agreement between predicted and experimental fuel consumption and NOx emissions....

A Fundamental Model for Predicting Fuel Consumption, NOx and HC Emissions of the Conventional Spark-Ignited Engine

Phenomenological models for reciprocating internal combustion engines

Measured amounts of oil were added to the engine cylinder of a single-cylinder CFR engine to determine the effect of oil layers on exhaust hydrocarbon emissions. The exhaust hydrocarbon concentration increased in proportion to the amount of oil added when the engine was fueled on isooctane. Addition of 0·6 cm3 of oil produced an increase of 1000 ppmC in exhaust hydrocarbon emissions at a coolant temperature of 320°K. Gas chromatographic analysis of the exhaust determined that fuel and fuel oxidation species, not oil oxidation products, were responsible for most of the increase. Similar experiments performed with propane fuel showed no increase in exhaust emissions when oil was added to the cylinder. These measurements have determined that the increase in tailpipe hydrocarbon concentration consists of fuel related species and is proportional to both the amount of oil added and the solubility of the fuel in the oil. Thus, we believe that the principal source of this increase in exhaust hydrocarbon ...

G. A. Lavoie

Papers

A super-extended zel'dovich mechanism for nox modeling and engine calibration

Modeling of HCCI Combustion and Emissions Using Detailed Chemistry

A Fundamental Model for Predicting Fuel Consumption, NOx and HC Emissions of the Conventional Spark-Ignited Engine

Phenomenological models for reciprocating internal combustion engines

The Effect of Oil Layers on the Hydrocarbon Emissions from Spark-Ignited Engines