G
Gennadii V. Shilov
Researcher at Russian Academy of Sciences
Publications - 76
Citations - 686
Gennadii V. Shilov is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Crystal structure & Monoclinic crystal system. The author has an hindex of 14, co-authored 76 publications receiving 586 citations. Previous affiliations of Gennadii V. Shilov include Southern Federal University.
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Journal ArticleDOI
Synthesis and the reactions of trifluoromethylated 1,2,3-triketones 2-(het)arylhydrazones and 4,7-dihydroazolo[5,1-c]triazines
Olga G. Khudina,Evgeny V. Shchegolkov,Ya. V. Burgart,M. I. Kodess,Olga N. Kazheva,A. N. Chekhlov,Gennadii V. Shilov,Oleg A. Dyachenko,V. I. Saloutin,Oleg N. Chupakhin +9 more
TL;DR: In this article, the long-range coupling constants (JF-H) of 1-methyl pyrazoles and the chemical shifts of trifluoromethyl groups in the 19F NMR spectra were used for the determination of regio-isomeric structures of mono(trifluorsophyl)-substituted pyrazole.
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Mesomeric tautomerism of ligand is a novel pathway for synthesis of cationic dinitrosyl iron complexes: Х-ray structure and properties of nitrosyl complex with thiourea
Nataliya A. Sanina,Sergey M. Aldoshin,Natal’ya Yu. Shmatko,Denis V. Korchagin,Gennadii V. Shilov,Nikolay S. Ovanesyan,Alexander V. Kulikov +6 more
TL;DR: In this article, a new cationic dinitrosyl iron complex (DNIC) with thiourea of the formula [Fe(SС(NH 2 ) 2 (NO) 2 ]Cl·H 2 O ( I ) has been obtained in the reaction of aqueous solutions of salts Na 2 [Fe 2 (S 2 O 3 ) 2
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Bifunctional Materials Based on the Photochromic Cation [RuNO(NH3)5]3+ with Paramagnetic Metal Complex Anions
Lyudmila A. Kushch,Lyudmila S. Kurochkina,Eduard B. Yagubskii,Gennadii V. Shilov,Sergei M. Aldoshin,V. A. Emel’yanov,Yurii N. Shvachko,Vladimir S. Mironov,Dominik Schaniel,Theo Woike,Chiara Carbonera,Corine Mathonière +11 more
TL;DR: In this article, the synthesis of a series of compounds containing the photochromic mononitrosyl cation, [RuNO(NH3)5]3+ and metal complex paramagnetic anions [M(CN)6]3− [M = Cr (1), Fe(2)], [M (ox)3]3-
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Nitrosyl iron complexes with enhanced NO donating ability: synthesis, structure and properties of a new type of salt with the DNIC cations [Fe(SC(NH2)2)2(NO)2]+
Nataliya A. Sanina,Sergey M. Aldoshin,Natal’ya Yu. Shmatko,Denis V. Korchagin,Gennadii V. Shilov,Ekaterine V. Knyazkina,Nikolay S. Ovanesyan,Alexander V. Kulikov +7 more
TL;DR: In this paper, the authors showed feasibility for the synthesis of water-soluble hybrid NO-generating complexes, which contain the NO groups both in the cationic and anionic sublattices and provide the control of the NO release kinetics.
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A new member of the cationic dinitrosyl iron complexes family incorporating N-ethylthiourea is effective against human HeLa and MCF-7 tumor cell lines
Nataliya A. Sanina,Natal’ya Yu. Shmatko,Denis V. Korchagin,Gennadii V. Shilov,Alexey A. Terent’ev,Tatyana S. Stupina,A. A. Balakina,Natal’ya V. Komleva,Nikolay S. Ovanesyan,Alexander V. Kulikov,Sergey M. Aldoshin +10 more
TL;DR: The cytotoxicity of I against HeLa, breast cancer, and non-immortalized cell lines is similar to that of anticancer agents currently used clinically (platinum complexes), but I is 10 times less toxic in normal cells.