G
Graham E. Dobereiner
Researcher at Temple University
Publications - 35
Citations - 2785
Graham E. Dobereiner is an academic researcher from Temple University. The author has contributed to research in topics: Catalysis & Aryl. The author has an hindex of 17, co-authored 32 publications receiving 2473 citations. Previous affiliations of Graham E. Dobereiner include Brandeis University & Scripps Research Institute.
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Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis.
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Secondary coordination sphere interactions facilitate the insertion step in an iridium(III) CO2 reduction catalyst.
TL;DR: A simple model for predicting the thermodynamic favorability of CO(2) insertion into Ir(III) hydrides is developed and it is demonstrated that with a hydrogen bond donor in the secondary coordination sphere it is possible to isolate a formate product from this reaction.
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Iridium-catalyzed hydrogenation of N-heterocyclic compounds under mild conditions by an outer-sphere pathway.
Graham E. Dobereiner,Ainara Nova,Nathan D. Schley,Nilay Hazari,Scott J. Miller,Odile Eisenstein,Robert H. Crabtree +6 more
TL;DR: Air- and moisture-stable iridium(I) NHC catalyst precursors that are active for reduction of a wide variety of quinolines having functionalities at the 2, 6, and 8- positions are reported.
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Oxidative Synthesis of Amides and Pyrroles via Dehydrogenative Alcohol Oxidation by Ruthenium Diphosphine Diamine Complexes
TL;DR: A series of ruthenium complexes can perform acceptorless dehydrogenation of diols as well as the reaction of amines and alcohols to form ester, lactam, and amide products.
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An Experimental−Theoretical Study of the Factors That Affect the Switch between Ruthenium-Catalyzed Dehydrogenative Amide Formation versus Amine Alkylation
Ainara Nova,David Balcells,Nathan D. Schley,Graham E. Dobereiner,Robert H. Crabtree,Odile Eisenstein +5 more
TL;DR: In this article, a ruthenium-II diamine complex can catalyze the intramolecular cyclization of amino alcohols H2N(CH2)nOH via two pathways: (i) one yields the cyclic secondary amine by a redox-neutral hydrogen-borrowing route with loss of water; and (ii) the corresponding cyclic amide by a net oxidation involving loss of H2.