https://www.cell.com/chem/pdf/S2451-9294(20)30631-8.pdf

A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide

Ultraviolet radiation (UVR) and noise are the ubiquitous environmental hazards with considerable detrimental effects on the physiological and psychological health of humans. Exploiting efficient protective materials that can be extensively used in daily life for simultaneous anti-UVR and noise mitigation will be of crucial importance, but it is still a significant challenge in materials design. Herein, we developed a series of protective textiles for efficient anti-UVR and noise reduction via MOFs nanocrystal-modified cotton textiles. The formation of MOFs@cotton textiles was confirmed by using electron microscopy, X-ray diffraction, infrared spectroscopy, and X-ray photoelectron spectroscopy. The fabricated MOFs@cotton textiles exhibited substantial improvement in the UVR blocking and acoustic absorption properties compared to blank cotton textiles. Therefore, this work provides a good strategy for designing and preparing multifunctional protective textiles.

Multifunctional Textiles/Metal−Organic Frameworks Composites for Efficient Ultraviolet Radiation Blocking and Noise Reduction

The efficient and safe capture of radioactive iodine (129I or 131I) is of great significance in nuclear waste disposal. Here, we report millimeter-scale poly(ether sulfone) composite beads loaded with porous Cu-BTC [Cu3(BTC)2, BTC = 1,3,5-benzenetricarboxylate] (Cu-BTC@PES), prepared by a phase inversion method for the removal of volatile iodine. Three kinds of Cu-BTC@PES composite beads were obtained with different Cu-BTC contents of 48.6, 60.2, and 71.9%, respectively. While maintaining crystallinity, the composite beads exhibited higher I2 vapor adsorption capacity (639 mg/g) in the form of iodine molecules. The iodine absorption up to 260 mg/g and the adsorption was followed Langmuir isotherm and pseudo-second-order kinetic model. Furthermore, the composite beads can still absorb more than 85% of iodine after 3 cycles of regeneration with excellent recyclability. The resulting Cu-BTC@PES composite beads show great potential for the sustainable removal of radioactive iodine.

Controllable Synthesis of Porous Cu-BTC@polymer Composite Beads for Iodine Capture

Capture of iodide from wastewater by effective adsorptive membrane synthesized from MIL-125-NH2 and cross-linked chitosan

Two novel thorium-based metal-organic frameworks (MOFs), namely Th-SINAP-7 and Th-SINAP-8, have been synthesized via the solvothermal reactions of thorium nitrate and 1,4- or 2,6-naphthalenedicarboxylic acid in the presence of acid modulators. Bearing the rigid aromatic architectures, Th-SINAP-7 and Th-SINAP-8 exhibit exceptional chemical (from pH 1 to 12) and thermal stabilities (up to 520 °C), as well as ionizing radioresistance (2 × 105 Gy β and γ irradiations). The highly porous nature and conjugated π-electrons of naphthalene on the organic linkers endow high affinity of both MOFs toward I2 molecules owning to the charge transfer between π-electrons of the host networks and the guest iodine molecules, as evidenced by combined techniques including of FTIR, PXRD, SEM-EDS, UV-vis spectroscopy, XPS, and Raman spectroscopy. Particularly, Th-SINAP-8 can efficiently remove >99% I2 from cyclohexane solution and exhibit guest uptake of iodine vapor with an adsorption capacity of 473 mg/g.

Guanghui Lin

Papers

Controllable Synthesis of Porous Cu-BTC@polymer Composite Beads for Iodine Capture

Efficient capture of iodine by a polysulfide-inserted inorganic NiTi-layered double hydroxides

Superior electrochemcial performances of core–shell structured vanadium oxide@vanadium carbide composites for Li-ion storage

Facile fabrication of 3D flower-like V2Al1-CT as an anode for lithium-ion batteries

Preparation and thermophysical properties of a novel dual-phase and single-phase rare-earth-zirconate high-entropy ceramics