Haipeng Wu

TL;DR: The analysis on the electrostatic potential demonstrates that although the pentagonal bipyramidal D5h is one of the ideal configurations expected, the electron density of the donor atoms from the different hybridizations and other functional groups, outside the first sphere, should also be considered in the rational design of promising molecular magnets.

TL;DR: In this article, a terbium-based metal-organic framework (Tb-MOF) was used as a fluorescent probe for metal ion detection, which can be used to detect Fe3+ and Al3+ without interference.

TL;DR: In this paper, the magnetic properties of Dy(III-SIMs were investigated by ab initio calculations and the magnetic anisotropy of 1−4 was investigated by showing that the capping ligands could play an important role in the fine tuning of the SMM property via an effect on the equatorial electrostatic potential.

TL;DR: The present work indicates that fabricating a redox-active organic molecule in functionalized MOFs offer a feasible strategy to design high-stable electroactive MOFs for construction of electrochemical biosensors with simplicity, high selectivity and sensitivity.

TL;DR: A dinuclear DyIII iodine-bridged single-molecule magnet self-assembled by cis/trans coordination chemistry that displays a large anisotropy barrier and the local transverse field at the trans site provides a model for thorough understanding of the effect of electronic structure on the magnetic behavior of lanthanide complexes.