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Showing papers by "Harry R. Allcock published in 1977"






Journal ArticleDOI
TL;DR: The first stable, high molecular weight phosphazene polymers that contain alkyl- or aryl- groups bonded directly to phosphorus have been synthesized by the interaction of organolithium or dialkylmagnesium reagents with poly-(difluorophosphazene).
Abstract: : The first stable, high molecular weight phosphazene polymers that contain alkyl- or aryl- groups bonded directly to phosphorus have been synthesized by the interaction of organolithium or dialkylmagnesium reagents with poly-(difluorophosphazene). The polymers are elastomers or tough, flexible, film-forming materials.

31 citations


Journal ArticleDOI
TL;DR: In this paper, a hochpolymeres system with einem aus alternierenden Phosphor and Stickstoffatomen aufgebauten anorganischen Gerust verspricht viele der Probleme zu losen.
Abstract: Ein hochpolymeres System mit einem aus alternierenden Phosphor- und Stickstoffatomen aufgebauten anorganischen Gerust verspricht viele der Probleme zu losen, die bei konventionellen organischen Polymeren auftreten Der folgende Aufsatz gibt einen Uberblick uber die Chemie, die Struktur sowie die biomedizinischen und technologischen Aspekte dieser Polymere

16 citations


Patent
02 May 1977
TL;DR: A cis-complex or -salt of a square planar platinum compound and a nitrogen containing oligomer or polymer prepared by reacting a platinum (II) compound with a nitrogen-containing polymer in an organic solvent or an acidic aqueous medium is used for treating animal malignant tumor cells sensitive to cis-square planar polysilicon compounds.
Abstract: A cis- complex or -salt of a square planar platinum compound and a nitrogen containing oligomer or polymer prepared by reacting a platinum (II) compound with a nitrogen containing oligomer or polymer in an organic solvent or an acidic aqueous medium, said complex or salt being useful for treating animal malignant tumor cells sensitive to cis-square planar platinum compounds.

15 citations




Journal ArticleDOI
TL;DR: The first stable, high molecular weight phosphazene polymers that contain alkyl- or aryl- groups bonded directly to phosphorus have been synthesized by the interaction of organolithium or dialkylmagnesium reagents with poly-(difluorophosphazene).
Abstract: : The first stable, high molecular weight phosphazene polymers that contain alkyl- or aryl- groups bonded directly to phosphorus have been synthesized by the interaction of organolithium or dialkylmagnesium reagents with poly-(difluorophosphazene). The polymers are elastomers or tough, flexible, film-forming materials.